甲基紫褪色光度法测定电镀废水中微量的铜

研究了在HNO3介质 ,95℃沸水浴中 ,Cu2 + 催化过氧化氢氧化甲基紫褪色反应的适宜条件及影响因素 ,据此建立了动力学褪色光度法测定微量Cu2 + 的新方法。方法的线性范围为 0～ 12 0 μg L ,表观摩尔吸光系数为 2 88× 10 5L mol·cm ,最大吸收波长为 5 80nm ,方法的检出限为 1 79× 10 - 1 0 μg L。该法应用于电镀废水中铜的测定 ,结果令人满意。     

The effect of heating temperature of thin film transistor-liquid crystal display (TFT-LCD) optical waste glass as a partial substitute partial for clay in eco-brick

In order to fulfill the current WEEE directives, the traditional approach to manage thin film transistor-liquid crystal display (TFT-LCD) waste glass is inadequate. It is a serious opportunity to achieve resource conservation, reduction, stabilization and safety of management of TFT-LCD in the near future. To assist in achieving these goals, this study investigated the sintering characteristics and material properties of TFT-LCD waste glass, which can be pulverized and ground and subsequently blended with clay, at various substitution levels (0–40%) and finally fired from 800 °C to 1000 °C to make eco-brick. The brick thus produced was analyzed to determine variations in weight losses on ignition, 24-h absorption, bulk density, shrinkage, compressive strength and microstructure changes. The results for specific gravity, water adsorption, and compressive strength revealed that bricks made from mixtures containing TFT-LCD waste glass met the general requirements for bricks. The advantages of less water absorption, less weight loss on ignition, and a gain in compressive strength in the clay-TFT-LCD waste glass bricks should encourage the use of TFT-LCD waste glass as a brick additive.     

辽东湾海冰晶体结构及其内部叶绿素的初步研究

本文介绍了１９９６年冬季首次辽东湾生态环境调查中的海洋背景条件。扼要地阐述了辽东湾海冰一般概况，分析辽东湾冰样晶体结构、存储条件及其与冰内和冰下海水叶绿素之间的关系。辽东湾冰内叶绿素符合其它结冰海区的一般规律。根据辽东湾冰层底部实测盐度变化规律阐明海冰对冰下海水营养盐的贡献。最后对深入开展结冰海区生态环境调查工作的技术、侧重点和意义做了讨论。     

天然水体及生活饮用水中铝的含量及形态分布

采用ＰＣＶ络合比色法和Ｆｅｒｒｏｎ逐时络合比色法，选取３种典型环境中的水体为研究对象；江西德兴铜矿地区的乐安江，白洋淀地区以及从源水，自来水到铝锅煮沸水序列水样，着重分析其中铝的含量及其形态分布，并讨论了铝的含量及其形态的变化对３种典型环境的影响。     

利用粉煤灰制备高纯超细氧化铝粉体的研究

利用粉煤灰为原料制备高纯超细氧化铝粉体。给出了采用硅酸二钙晶相转变自粉化、高效分散剂———碳化法从粉煤灰中制备氧化铝方法的工艺路线 ,确定了从粉煤灰制备高纯超细氧化铝粉体的最佳工艺条件 ,为粉煤灰的高价值利用开辟了一条新途径     

Measurement of the pesticide methomyl by modified quartz crystal nanobalance with molecularly imprinted polymer

A simple and cost-effective analysis method based on quartz crystal nanobalance (QCN) coated with a molecularly imprinted polymer (MIP) for measurement of methomyl was investigated. In the first part of this study, a sensitive, selective and reliable quartz crystal nanobalance (QCN) sensor was designed for the selective determination of methomyl in aqueous solutions. In the second part, in order to demonstrate the applicability and performance of the fabricated sensor in the real world situation, it was successfully applied for the determination of methomyl residual in photo catalytic degradation by ZnO powders in aqueous solutions. The fabricated sensor presents a high selectivity and sensitivity (4.56 Hz per mg L^?1) for methomyl and it can be used for determination of methomyl concentration ranged between 1 to 45 mg L^?1. Furthermore, good reproducibility, R.S.D. = 2.14% (n = 5) was observed. To investigate the performance of the sensor, the change in the insecticide concentration during the photocatalytic degradation of methomyl by ZnO was investigated by QCN and UV/Vis spectroscopy. Results obtained from QCN sensor and UV/Vis spectroscopy measurement are in good mutual agreement. So the fabricated sensor may provide an efficient, low cost, easy-to-use method for the in-field evaluation of specific targeted analytes in aqueous solutions which in turn may lead to improved food and water safety.     

平板显示器回收的新挑战

显示屏（监视器和电视机）经历了从阴极射线管到平板显示器技术的快速变化。截至目前为止,只有少量的平板显示器已记录在废物收集点。平板显示器的数量越来越多,在未来需要足够的用于回收的基础设施。本文旨在通过液晶显示屏幕的回收对经济影响的案例研究来提供数量、成分、回收利用技术和经验的基本数据。对于组件和材料也适用于其他类型的电子产品,如黑色金属和有色金属,印刷电路板或电缆,回收途径和技术是众所周知的和可用的。目前,液晶显示器（LCD）在欧洲不回收。处置时,例如,通过焚烧,有价值的材料,其成分是不再可用。例如：铟具有重要战略意义的应用,如,太阳能光伏作为一种稀缺资源。液晶显示器在欧洲具有回收基础设施,因此是有用的。     

电催化氧化法处理阳离子染料废水的试验研究

以结晶紫作为阳离子染料,采用电催化氧化法对阳离子染料溶液进行了电解脱色处理试验,研究了电流密度、电解质种类、电解质浓度、pH值等对该溶液脱色率的影响,测定了电解时溶液中生成的余氯浓度和溶液的紫外-可见吸收光谱曲线,并对不同电解时间的溶液的吸光度进行了归一化计算。结果表明:随着电解时间的延长,水溶液中活性氯浓度不断上升,经一定时间后达到最大值;在电催化和活性氯的协同作用下,阳离子染料结晶紫分子中的大π共轭体系被破坏、苯环结构基本瓦解,溶液快速脱色;在电流密度为5.1mA/cm2、NaCl浓度为4g/L、pH值为9.41的条件下,初始浓度为100mg/L的结晶紫溶液经过20min的电解,其脱色率可高达98.31%。     

Resistance and biosorption mechanism of silver ions by Bacillus cereus biomass

Biosorption of silver ions onto Bacillus cereus biomass was investigated. Overall kinetic experiments were performed for the determination of the necessary contact time for the attainment of equilibrium. It was found that the overall biosorption process was best described by pseudo second-order kinetic model. The crystals detected by scanning electron microscope and X-ray photoelectron spectroscopy suggested the precipitation was a possible mechanism of biosorption. The molecular genetics of silver resistance of B. cereus biomass was also detected and illustrated by a whole cell sensor tool.