Stability of a Coal Waste Artificial Reef

The feasibility of using U.K. coal-fired power station waste materials for artificial reef production is being examined. in June, 1989, an experimental artificial reef was constructed in Poole Bay, off the central south coast of the U.K., using three different mixtures of pulverised fuel ash (PFA), flue gas desulphurisation (FGD) gypsum and slurry, stabilized with cement and formed into blocks. Fifty tonnes of 40 × 20 × 20 cm blocks were formed into eight conical reef units replicating three different PFA/gypsum mixtures and one concrete control. the reef structure is 10m below chart datum on a flat sandy sea-bed.

Combustion of coal concentrates the heavy metal content in the resultant ash. the purpose of stabilization of the ash as blocks is twofold: to immobilize heavy metals (or other components) and to provide hard substratum for the attachment of organisms. to examine the effectiveness of this stabilization and hence the environmental compatibility of the block materials, heavy metal (Cd, Cr, Cu, Pb, Mn, Ni, Zn) content of the blocks has been monitored routinely over two years, to determine leaching rates. Sectional profiles indicate partial replacement of calcium content by magnesium. Associated with this there has also been some redistribution of heavy metals. Only in the case of cadmium has there been a detectable loss from the surface of blocks. Chromium and manganese concentrations appear to have increased. the metal content of the reef epibiota (including ascidians, Ascidia mentula; hydroids, Halecium spp.; bryozoans, Bugula spp. and red algae) growing on the ash blocks has been compared to that of epibiota attached to the concrete controls and surrounding sea-bed. to date no evidence of excess bioaccumulation of metals has been detected.

The physical integrity of the ash reef blocks has been maintained. There is evidence that the blocks are increasing in compressive strength.

An indication of the fishery enhancement potential of the experimental structure is given by the presence of eight commercially fished species (crustaceans and molluscs) including lobsters (Homarus gammarus).     

焚烧飞灰重金属含量及浸出长期变化规律研究

通过对24个飞灰样品的重金属全量消解和高精度X射线荧光光谱法（HDXRF）快速检测结果进行线性回归分析,发现HDXRF法可较准确测定飞灰中Cu、Pb、Zn、Ni和Cd含量（线性回归决定系数R²³0.90）.采用HDXRF法对某焚烧厂飞灰重金属含量6个月快速检测及浸出毒性测定数据统计分析发现：飞灰重金属月均含量较稳定（变异系数CV<0.14）但日均含量波动较大（CV>2.54）;飞灰中Pb、Cu和Zn含量呈正相关（相关系数r>0.78）;金属浸出浓度受浸出液终点pH值影响显著,超标频率依次为Pb（68.9%）、Cd（66.1%）、Ni（24.0%）、Cu（14.2%）和Zn（1.6%）.短期飞灰金属含量和浸出毒性数据受焚烧工况,烟气处理工况和垃圾组分等多种因素共同影响,不具有代表性.为评估垃圾分类源头削减重金属效果,建议采用快速检测方法对焚烧飞灰重金属含量进行长期监测.     

Coupling mechanism of activated carbon mixed with dust for flue gas desulfurization and denitrification

To clarify the effect of coking dust, sintering dust and fly ash on the activity of activated carbon for various industrial flue gas desulfurization and denitrification, the coupling mechanism of the mixed activated carbon and dust was investigated to provide theoretical reference for the stable operation. The results show that coking dust had 34% desulfurization efficiency and 10% denitrification efficiency; correspondingly, sintering dust and fly ash had no obvious desulfurization and denitrification activities. For the mixture of activated carbon and dust, the coking dust reduced the desulfurization and denitrification efficiencies by blocking the pores of activated carbon, and its inhibiting effect on activated carbon was larger than its own desulfurization and denitrification activity. The sintering dust also reduced the desulfurization efficiency on the activated carbon while enhancing the denitrification efficiency. Fly ash blocked the pores of activated carbon and reduced its reaction activity. The reaction activity of coking dust mainly came from the surface functional groups, similar to that of activated carbon. The reaction activity of sintering dust mainly came from the oxidative property of Fe₂O₃, which oxidized NO to NO₂ and promoted the fast selectively catalytic reduction (SCR) of NO to form N₂. Sintering dust was activated by the joint action of activated carbon, and both had a coupling function. Sintering dust enhanced the adsorption and oxidation of NO, and activated carbon further promoted the reduction of NO_x by NH₃; thus, the denitrification efficiency increased by 5%-7% on the activated carbon.     

某垃圾焚烧厂投产前后周边土壤二英类化合物的分布

为研究垃圾焚烧厂运行对周边土壤二英类化合物（PCDD/Fs）含量的影响,采集了珠三角地区某垃圾焚烧厂投产前和投产后周边土壤样品,分析研究了该垃圾焚烧厂运行对周边土壤中PCDD/Fs含量和组分的变化.结果表明:①2012年（投产前）珠三角地区某垃圾焚烧厂周边土壤PCDD/Fs含量较低,范围为163~591 ng/kg（毒性当量范围为0.198~0.863 ng I-TEQ/kg,I-TEQ为国际毒性当量因子折算的毒性当量值）;2017—2019年（投产后）周边土壤PCDD/Fs含量范围为151~1.75×103 ng/kg（毒性当量范围为0.812~3.88 ng I-TEQ/kg）,与其他研究相比处于较低的水平.②投产后,距该垃圾焚烧厂较近（1.5 km）的采样点（S1）土壤PCDD/Fs含量逐年增长,在较远（5.2 km）但人口较密集的采样点（S3）土壤PCDD/Fs含量整体较高,但呈逐年下降趋势.③投产后,土壤中的17种PCDD/Fs单体组分中,毒性当量贡献率最高的单体为八氯二苯并二英（OCDD）和2,3,4,7,8-五氯二苯并呋喃（2,3,4,7,8-PeCDF）,二者毒性当量贡献率范围为15.7%~45.4%.④在同一采样点土壤PCDD/Fs单体组分年间差异不明显,但同一年份不同采样点差异明显.研究显示,目前该垃圾焚烧厂周边土壤PCDD/Fs含量较低,但仍需要长期监测其可能带来的风险.      

Fly-ash-induced oxidative stress and tolerance in Prosopis juliflora L. grown on different amended substrates

Field experiments were conducted to study the impact of metal accumulation on malondialdehyde (MDA), cysteine and non-protein thiol (NPSH) contents in the plants of Prosopis juliflora grown on the fly ash (FA) amended with soil, blue green algae (BGA) biofertilizer, farm yard manure, press mud and Rhizobium inoculation. The analysis of data revealed that the level of MDA, cysteine and NPSH was higher in the roots of the plant than leaves, which was found positively correlated with metal accumulation. An increase of 361.14, 64.25 and 305.62% in MDA, cysteine and NPSH contents, respectively was observed after 45 days in the roots of the plants grown in 100% FA as compared to 100% garden soil (GS). The level of MDA, cysteine and NPSH was found less in the plants grown on various amendments of FA showing ameliorating effect on the toxicity induced due to the accumulation of metals. The decrease in MDA, cysteine and NPSH contents was higher in Rhizobium-inoculated plants as compared to uninoculated plants grown on 100% FA. The results showed a high tolerance potential of the plant, which is further increased by inoculating the plant with FA-tolerant Rhizobium showing feasibility of using P. juliflora in environmental monitoring of FA landfills.     

CFB锅炉燃烧高硫石油焦的灰渣综合利用研究

循环流化床锅炉在燃烧含硫石油焦时,通过加入石灰石在燃烧的过程中以固态的形式脱硫,燃烧后将产生大量的灰渣,过去处理灰渣最通常的方式是作土地填埋。从灰渣的化学、物理特性试验研究出发,寻找循环流化床灰渣在建筑材料、农业应用和水泥添加剂方面的利用途径,研究了更加经济有效的灰渣处理方法。     

粉煤灰预处理及其对染料单体脱色效果的研究

介绍了一种粉煤灰预处理的方法-用8mol/L的H2SO4处理，可较好地改善其表面状况，并用预处理后的粉煤灰对染料单体进行脱色试验，寻找了最佳的处理方案，脱色效果较好，建立了Langmuir吸附等温模型。探讨了其脱色机理，为实际开发利用粉煤灰处理印染废水提供基础研究。     

粉煤灰/工业污泥烧结陶粒的制备与应用

以粉煤灰和工业污水处理站的剩余污泥为主要原材料，采用烧结法研制复合陶粒。分析了不同配方和不同烧结温度对陶粒性能的影响，以陶粒吸水率．容重为评价指标确定最佳配比和最佳烧结温度。提出用陶粒铺设景观水底，治理城市水体．并对其进行了可行性分析。粉煤灰／污泥陶粒的容重为0．79～0．9g／cm^3，吸水率为68．95％-80．01％。陶粒对水中氨氮和总磷吸附容量分别为0．03～0．05mg／g和0．01-0.02mg／g。     

一种粉煤灰加气砼清洁生产新技术的研究

针对粉煤灰加气砼砌块生产的特点，分析了粉煤灰加气砼清洁生产的基本技术，设计了一种粉煤灰加气砼破碎磨粉车间清洁生产新方法，该方法能实现粉煤灰加气砼破碎磨粉车间湿式去尘，并有效提高水、气资源的综合利用率，该方法也可用于其它粉尘排放量大的场所除尘。     

城市固体垃圾焚烧的二次污染控制实现技术

由于城市固体垃圾的复杂多变性及不确定性,难以实现对垃圾的充分燃烧,常因控制不当而产生二次污染。针对二次污染控制问题,文章采用变频调速技术与智能控制技术相结合,提高系统的响应速度,满足垃圾焚烧对空(气)燃(料)比的严格需要,有效保证了垃圾的充分燃烧,减少了烟气对大气环境的二次污染。在讨论城市固体垃圾特性基础上,分析了二次污染产生的条件,探讨了优化燃烧过程的控制策略、风量调节方式、系统构架及相关技术问题。