徐州市大气PM2.5与O3作用关系的季节变化

通过2013~2017年徐州市环境监测资料分析季风影响下主要大气复合污染物PM_2.5和O₃的相关性,并基于气象观测资料进一步探究PM_2.5和O₃相互作用机制的季节变化特征.结果表明：夏季风季节,PM_2.5和O₃呈正相关,相关系数高达0.56;冬季风季节,PM_2.5和O₃呈负相关,相关系数为-0.34,均通过了99%的置信检验,表明徐州市PM_2.5和O₃相互作用呈现相反的季节变化.夏季风季节,太阳辐射强,气温较高,大气氧化性较强,O₃主导大气氧化性,大气氧化性通过促进二次颗粒物生成使得PM_2.5浓度升高,夏季风季节以O₃对PM_2.5的促进作用主导城市大气复合污染变化;冬季风季节,太阳辐射弱,气温较低,大气氧化性较弱,高浓度的PM_2.5削弱太阳辐射抑制大气光化学,导致O₃生成率降低,冬季风季节以PM_2.5对O₃的抑制作用主导城市大气复合污染变化.     

Influence of human activity and monsoon dynamics on spatial and temporal hydrochemistry in tropical coastal waters (Sanya Bay,South China Sea)

Human activities and oceanic influences like mixing and/or upwelling define the hydrochemical and biological characteristics of coastal regions. In Sanya Bay, northern South China Sea, the balance between these two influences on spatial and temporal scales is poorly understood. The influence from human activities was due to discharge from Sanya River, whereas the most important marine influence was related to seasonal changes in hydrodynamics. Spatial differences (p<0.05) in total nitrogen (TN) and chlorophyll-a (Chl-a) were observed. Seasonal differences were observed for temperature and nutrients. Human activities are the dominant factor influemcing hydrochemistry in the inner bay. This region exhibited the maximum influence of discharge from Saya River as estimated by higher nutrient levels. Oceanic influences like upwelling and mixing caused by monsoons are the dominant factors influencing hydrochemistry in the central and outer bay. Both human activities and oceanic influences play important roles in coastal ecosystems in Sanya Bay. This study has defined these characteristics so that better management policies can be enacted.