全文获取类型
收费全文 | 373篇 |
免费 | 47篇 |
国内免费 | 241篇 |
专业分类
安全科学 | 32篇 |
废物处理 | 39篇 |
环保管理 | 30篇 |
综合类 | 363篇 |
基础理论 | 68篇 |
污染及防治 | 102篇 |
评价与监测 | 27篇 |
出版年
2023年 | 5篇 |
2021年 | 5篇 |
2020年 | 6篇 |
2019年 | 6篇 |
2018年 | 15篇 |
2017年 | 10篇 |
2016年 | 20篇 |
2015年 | 27篇 |
2014年 | 29篇 |
2013年 | 40篇 |
2012年 | 43篇 |
2011年 | 40篇 |
2010年 | 50篇 |
2009年 | 34篇 |
2008年 | 28篇 |
2007年 | 44篇 |
2006年 | 44篇 |
2005年 | 32篇 |
2004年 | 31篇 |
2003年 | 29篇 |
2002年 | 28篇 |
2001年 | 14篇 |
2000年 | 11篇 |
1999年 | 13篇 |
1998年 | 9篇 |
1997年 | 12篇 |
1996年 | 12篇 |
1995年 | 8篇 |
1994年 | 2篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1986年 | 3篇 |
排序方式: 共有661条查询结果,搜索用时 15 毫秒
1.
Photocatalytic degradation of phenol 总被引:3,自引:0,他引:3
In this study photocatalytic degradation of phenol in thepresence of UV irradiated TiO2 catalyst andH2O2was investigated. Effects of TiO2 andH2O2concentrations and pH on photocatalytic degradation were examined. The rate constants for photocatalytic degradation wereevaluated as a function of TiO2 and H2O2 concentrations and pH of the solution. It was found thatphotodegradation is an effective method for the removal of phenoland disappearance of phenol obeyed first order kinetics. The amount of CO2h produced during photocatalytic degradation wascorresponding to the complete mineralization. Photodegradationcan be an alternative method for the treatment of phenol containing wastewaters. 相似文献
2.
Phenol, like many other organic solvents, is toxic to micro-organisms even at low concentrations. However, some micro-organisms can withstand this toxicity to a certain concentration. To observe the uptake mechanism of phenol, bacteria were isolatedfrom a petroleum refinery effluent and identified. Study was carried out to understand the effect of varying sub-lethal concentrations of phenol, on all the isolated individual bacterial cultures. Out of the bacteria isolated, Serratia liquefaciens was found to tolerate phenol concentration up to 1500 mg l-1. A microbial consortium of the isolated bacteriawas formulated and immobilized. Individual cultures were also immobilized and uptake of phenol by the immobilized micro-organisms was observed in a nutrient-rich and nutrient-stressed medium containing phenol as a sole source of carbon. A time-dependent uptake of phenol was exhibited by the micro-organismsin nutrient-stressed medium, after which a sudden increase in phenol concentration occurred in the extracellular medium, till it reached back to the initial concentration. This was attributedto an active efflux mechanism adopted by the micro-organisms to withstand the toxic shock. 相似文献
3.
Li Ning Li Guangming Yao Zhenya Zhao Jianfu 《Frontiers of Environmental Science & Engineering in China》2007,1(2):190-195
Catalytic wet air oxidation (CWAO) is one of the most promising technologies for pollution abatement. Developing catalysts
with high activity and stability is crucial for the application of the CWAO process. The Mn/Ce complex oxide catalysts for
CWAO of high concentration phenol-containing wastewater were prepared by coprecipitation. The catalyst preparation conditions
were optimized by using an orthogonal layout method and single-factor experimental analysis. The Mn/Ce serial catalysts were
characterized by Brunauer-Emmett-Teller (BET) analysis and the metal cation leaching was measured by inductively coupled plasma
torch-atomic emission spectrometry (ICP-AES). The results show that the catalysts have high catalytic activities even at a
low temperature (80°C) and low oxygen partial pressure (0.5 MPa) in a batch reactor. The metallic ion leaching is comparatively
low (Mn<6.577 mg/L and Ce<0.6910 mg/L, respectively) in the CWAO process. The phenol, CODCr, and TOC removal efficiencies in the solution exceed 98.5% using the optimal catalyst (named CSP). The new catalyst would
have a promising application in CWAO treatment of high concentration organic wastewater.
Translated from Techniques and Equipment for Environmental Pollution Control, 2005, 6(2): 40–44 [译自: 环境污染治理技术与设备] 相似文献
4.
含酚废水治理方法的研究 总被引:2,自引:0,他引:2
根据含酚废水的性质,用ClO2氧化除酚,ZL—1和聚丙烯酰胺(PAM)混凝沉降除悬浮物的方法处理该废水。实验结果表明,经处理后废水中的主要污染物酚、焦油和悬浮物等去除率都很高,该水可以满足循环使用的要求。 相似文献
5.
6.
基于表征成键原子的生物活性特征值Ai构建取代苯酚的自相关拓扑指数tT,并以0T1、T为结构描述符,分别建立了取代苯酚诱发浮萍萎黄、对日本长腿蛙蝌蚪的QSAR模型:pC=-2.4591+0.51730T-6.3888×10-21T,r=0.9778;24h-LC50=2.1269+1.1013×10-20T+3.4552×10-41T2,r=0.9676.它们的估算结果均优于文献结果,用Jackknife法检验,以上模型具有总体稳健性。 相似文献
7.
热带假丝酵母8953菌株对苯酚的降解特性研究 总被引:6,自引:1,他引:6
实验室分离的一株热带假丝酵母(编号为8953)具有较强的苯酚降解能力,并可以利用苯酚、间苯二酚、联苯胺等芳烃为唯一碳源和能源生长。该菌株在48h内可完全降解约14.88mmol/L苯酚,完全降解10.63mmol/L苯酚只需要24h,其降解苯酚浓度最高可达19.13mmol/L。在pH4~9,温度20℃~40℃范围内,苯酚浓度为10.0mmol/L条件下该菌株均保持100%的降解率。该菌株降解苯酚的最适pH范围为6.0~8.0,最适温度范围为28℃~30℃,最佳接种量为1%~3%,外源添加氮源能促进酵母生长和苯酚的降解。 相似文献
8.
9.
一株苯酚降解菌的分离和鉴定 总被引:42,自引:0,他引:42
:从工业废水中分离到一株高效降解苯酚的菌株PHEA 2 ,它能够在以苯酚为单一碳源和能源的无机培养基上生长 ,其最高苯酚降解率为 394nmol/ (mg·min) .经Biolog细菌自动鉴定仪鉴定 ,该菌株为醋酸钙不动杆菌 (Acinetobactercalcoaceti cus) .采用PCR扩增获得的该菌 16SrDNA片段 ,核苷酸序列分析结果表明 ,该菌株的 16SrDNA的核苷酸序列与醋酸钙不动杆菌同源性为 98% .在细菌系统发育分类学上 ,PHEA 2归属变形细菌γ亚类、不动杆菌属、醋酸钙不动杆菌 . 相似文献
10.
在兰州炼油化工添加剂厂烷基酚装置过滤工序改造设计中 ,通过优化流程、更新设备、改善计量等措施 ,达到了消除装置瓶颈、提高生产能力、节能降耗、保证安全及解决环境污染的目的 ,取得了良好的效果。 相似文献