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苯磺酰基环烷烃甲酸酯结构对发光菌的毒性影响 总被引:1,自引:0,他引:1
测定了一批具有大小不同碳环的的苯磺酰基环烷烃甲酸酯对发光菌的毒性数据,值得注意的是碳环大小的改变会影响化合物的毒性,碳环对毒性的影响按三元环〉四元环〉五元环〉六元环的顺序减小。 相似文献
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Biotransformation of nonylphenol ethoxylates during sewage treatment
under anaerobic and aerobic conditions 总被引:2,自引:0,他引:2
Biotransformation of nonylphenol ethoxylates (NPEOs) during continuous anaerobic sewage treatment was compared with the aerobic treatment of sewage spiked with 23 μmol/L technical NPEOs over a period of 90 d. Immediate degradation of NPEOs was observed under both anaerobic and aerobic conditions, indicating that the enzymes and bacteria required for NPEO degradation existed abundantly in both aerobic and anaerobic sludge. Both treatments achieved high removal (>92%) of the spiked NPEO9 mixture.Liquid chromatography-mass spectrometry (LC-MS) analysis showed that short-chain NPEOs (NPEO1-NPEO3) accumulated in anaerobic (2.01-2.56 μmol/L) and aerobic (1.62-2.03 μmol/L) effluents, with nonylphenol (NP) (0.24-0.31 μmol/L) as another group of metabolites in the anaerobic effluent, and nonylphenoxy carboxylates (NPECs) (2.79-3.30 μmol/L) in the aerobic effluent. Significant accumulation of NP in the anaerobic sludge and NPEO1-3 in the sludge of two reactors was observed. These results indicated that it was difficult to control these harmful metabolites in the conventional treatment processes. Denaturing gradient gel electrophoresis profiles of sludge samples support the speculation that the NPEO degradation bacteria might be the dominant indigenous species. 相似文献
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