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排序方式: 共有405条查询结果,搜索用时 15 毫秒
1.
Gabriela P. Mendes Vivian M.A. Magalhães Lélia C.R. Soares Rayanne M. Aranh Claudio A.O. Nascimento Marilda M.G.R. Viann Osvaldo Chiavone-Filho 《环境科学学报(英文版)》2020,32(4):67-77
Chemical oxidation was applied to an artificially contaminated soil with naphthalene (NAP). Evaluation of NAP distribution and mass reduction in soil, water and air phases was carried out through mass balance. Evaluation of NAP distribution and mass reduction in soil, water and air phases was carried out through mass balance. The importance of the air phase analysis was emphasized by demonstrating how NAP behaves in a sealed system over a 4 hr reaction period. Design of Experiments method was applied to the following variables: sodium persulfate concentration [SP], ferrous sulfate concentration [FeSO4], and pH. The system operated with a prefixed solid to liquid ratio of 1:2. The following conditions resulted in optimum NAP removal [SP] = 18.37 g/L, [FeSO4] = 4.25 g/L and pH = 3.00. At the end of the 4 hr reaction, 62% of NAP was degraded. In the soil phase, the chemical oxidation reduced the NAP concentration thus achieving levels which comply with Brazilian and USA environmental legislations. Besides the NAP partitioning view, the monitoring of each phase allowed the variabilities assessment over the process, refining the knowledge of mass reduction. Based on NAP distribution in the system, this study demonstrates the importance of evaluating the presence of semi-volatile and volatile organic compounds in the air phase during remediation, so that there is greater control of the system as to the distribution and presence of the contaminant in the environment. The results highlight the importance of treating the contaminant in all its phases at the contaminated site. 相似文献
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As a novel alternative to traditional perfluoroalkyl substances (PFASs), including perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS), hexafluoroproplyene oxide trimer acid (HFPO-TA) has been detected worldwide in surface water. Moreover, recent researches have demonstrated that HFPO-TA has stronger bioaccumulation potential and higher hepatotoxicity than PFOA. To treat these contaminants e.g. PFOA and PFOS, some photochemical techniques by adding exogenous substances had been reported. However, there is still no report for the behavior of HFPO-TA itself under direct UV irradiation. The current study investigated the photo-transformation of HFPO-TA under UV irradiation in aqueous solution. After 72 hr photoreaction, 75% degradation ratio and 25% defluorination ratio were achieved under ambient condition. Reducing active species, i.e., hydrated electrons and active hydrogen atoms, generated from water splitting played dominant roles in degradation of HFPO-TA, which was confirmed by different effects of reaction atmospheres and quenching experiments. A possible degradation pathway was proposed based on the products identification and theoretical calculations. In general, HFPO-TA would be transformed into shorter-chain PFASs, including hexafluoropropylene oxide dimer acid (HFPO-DA), perfluoropropionic acid (PFA) and trifluoroacetate (TFA). This research provides basic information for HFPO-TA photodegradation process and is essential to develop novel remediation techniques for HFPO-TA and other alternatives with similar structures. 相似文献
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生活垃圾生物处理的研究与展望 总被引:2,自引:0,他引:2
综述了国内外生活垃圾生物处理的研究进展和目前生活垃圾微生物研究水平,以及生活垃圾处理发展趋势与新动向,在此基础上提出了生活垃圾处理的建议和展望。 相似文献
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原生垃圾密度很小,为提高填埋垃圾堆体密实度、延长填埋场使用寿命,对填埋垃圾进行压实处理很重要。本文通过现场工程试验对影咱填埋垃圾堆体平面压实效果的主要因素进行了系统研究。实验结果表明:为取得最佳的垃圾堆体平面压实效果,最佳垃圾摊铺厚度在0.5m—0.7m之间,最佳机械行程次数为3次,增加碾压次数有利于提高垃圾堆体密实度,垃圾最佳含水率在30%——50%之间。 相似文献
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污染物的微生物毒性检验 总被引:2,自引:0,他引:2
从文献报导的10几种污染物毒性试验方法中,选择了脱氢酶活性、Microtox毒性、微生物呼吸率、以及降解动力学等4种方法,系统地比较,研究了其表示污染物对微生物的毒性效应的灵敏性,准确性,可靠性和实用性,研究结果应用于焦化废水、染化废水与黄浦江水样的检验表明,MTX方法能最好地反映污染物的微生物毒性,且操作简便,费时少,数据的解释也最为方便。 相似文献
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