全文获取类型
收费全文 | 1014篇 |
免费 | 40篇 |
国内免费 | 82篇 |
专业分类
安全科学 | 99篇 |
废物处理 | 17篇 |
环保管理 | 303篇 |
综合类 | 188篇 |
基础理论 | 316篇 |
环境理论 | 1篇 |
污染及防治 | 99篇 |
评价与监测 | 50篇 |
社会与环境 | 46篇 |
灾害及防治 | 17篇 |
出版年
2023年 | 17篇 |
2022年 | 11篇 |
2021年 | 29篇 |
2020年 | 30篇 |
2019年 | 21篇 |
2018年 | 10篇 |
2017年 | 21篇 |
2016年 | 35篇 |
2015年 | 33篇 |
2014年 | 25篇 |
2013年 | 64篇 |
2012年 | 27篇 |
2011年 | 76篇 |
2010年 | 45篇 |
2009年 | 82篇 |
2008年 | 61篇 |
2007年 | 51篇 |
2006年 | 70篇 |
2005年 | 46篇 |
2004年 | 33篇 |
2003年 | 35篇 |
2002年 | 31篇 |
2001年 | 23篇 |
2000年 | 26篇 |
1999年 | 15篇 |
1998年 | 22篇 |
1997年 | 17篇 |
1996年 | 16篇 |
1995年 | 14篇 |
1994年 | 10篇 |
1993年 | 11篇 |
1991年 | 5篇 |
1990年 | 7篇 |
1989年 | 8篇 |
1988年 | 6篇 |
1987年 | 9篇 |
1986年 | 6篇 |
1985年 | 7篇 |
1984年 | 4篇 |
1983年 | 6篇 |
1981年 | 9篇 |
1980年 | 7篇 |
1979年 | 12篇 |
1978年 | 6篇 |
1977年 | 5篇 |
1975年 | 3篇 |
1973年 | 5篇 |
1972年 | 7篇 |
1971年 | 5篇 |
1970年 | 3篇 |
排序方式: 共有1136条查询结果,搜索用时 31 毫秒
1.
Effluent from dyeing and finishing processes is an important source of water pollution. The effectiveness of bentonite, kaolinite and sediment from a local deposit in removing methylene blue as a cationic dye from aqueous solutions has been investigated. The adsorption equilibrium (isotherm) has been determined according to Freundlich and Langmuir equations. The optimum amount is 0.5 g for all adsorbents, and the optimum pH ranges are 2-8 for bentonite and 2-6 for kaolinite and sediment. With respect to kinetic modelling, the adsorption of methylene blue on various adsorbents was fitted to a second-order equation. Also, the thermodynamic parameters were determined. The negative free energy values indicate the feasibility of the process and spontaneous nature of adsorption. The positive ΔH° values indicate the endothermic nature of the process. Thus, Egyptian clay minerals and sediments have a great tendency to remove the dye from solutions. 相似文献
2.
3.
Lucie Tsamb Nicolas Cimetière Dominique Wolbert Olivier Corre Pierre Le Cloirec 《环境科学学报(英文版)》2020,32(1):112-122
Disinfection by-products(DBPs) are formed in swimming pools by the reactions of bather inputs with the disinfectant.Although a wide range of molecules has been identified within DBPs,only few kinetic rates have been reported.This study investigates the kinetics of chlorine consumption,chloroform formation and dichloroacetonitrile formation caused by human releases.Since the flux and main components of human inputs have been determined and formalized through Body Fluid Analogs(BFAs),it is possible to model the DBPs formation kinetics by studying a limited number of precursor molecules.For each parameter the individual contributions of BFA components have been quantified and kinetic rates have been determined,based on reaction mechanisms proposed in the literature.With a molar consumption of 4 mol Cl_2/mol,urea is confirmed as the major chlorine consumer in the BFA because of its high concentration in human releases.The higher reactivity of ammonia is however highlighted.Citric acid is responsible for most of the chloroform produced during BFA chlorination.Chloroform formation is relatively slow with a limiting rate constant determined at 5.50 × 10~(-3) L/mol/sec.L-histidine is the only precursor for dichloroacetonitrile in the BFA.This DBP is rapidly formed and its degradation by hydrolysis and by reaction with hypochlorite shortens its lifetime in the basin.Reaction rates of dichloroacetonitrile formation by L-histidine chlorination have been established based on the latest chlorination mechanisms proposed.Moreover,this study shows that the reactivity toward chlorine differs whether L-histidine is isolated or mixed with BFA components. 相似文献
4.
5.
Photoactive aluminum doped ZnO(AlZnO) was synthesized by sol-gel method.After that,AlZnO photocatalyst was deposited on five carbon-based materials(CBMs) using ultrasonic route followed by solid-state mixing using ball mill.The CBMs used were poly aniline(PANI),carbon nitride(CN),carbon nanotubes(CNT),graphene(G),and carbon nanofibers(CNF).The crystal phases,elemental compositions,morphological,and optical properties of the AlZnO@CBMs composites were investigated.Experimental results revealed that two of AlZnO@CBMs composites exhibited superior bleaching efficiency(100% removal) and photocatalytic stability(three cycles) for 50 μmol/L Methylene Blue(MB) contaminated water after 60 min irradiation in visible light at pH 6.5,0.7% H_2O_2,and 5 g/L inorganic salts.Under optimum conditions,AlZnO@CBMs nanocomposites were employed for the treatment of mixed dyestuffs composed of MB,Methyl Orange(MO),Astrazone Blue FRR(BB 69),and Rhodamine B(RhB) dyes under dark,ultraviolet,visible,and direct sunlight.For mixed dyestuffs,the AlZnO@G achieved the highest dye sorption capacity(60.91 μmol dye stuffs/g) with kinetic rate 8.22 × 10~(-3) min~(-1) in 90 min via multi-layer physisorption(Freundlich isotherm) on graphene sheet.In additions,AlZnO@CN offered the highest photo-kinetic rate(K_(photo)) of~54.1 × 10~(-3) min~(-1)(93.8% after 60 min) under direct sunlight.Furthermore,the selective radical trapping experiment confirmed that the holes and oxidative superoxide radicals are crucial on dyes photodegradation pathway.Owing to their superior performance,AlZnO@G and AlZnO@CN nanocomposites can offer an effective in-situ solar-assisted adsorption/photocatalytic remediation of textile wastewater effluents. 相似文献
6.
对熏烟扩散模式应用的探讨 总被引:5,自引:0,他引:5
工程上应用的大气污染物扩散模式中 ,熏烟模式由于其非定常性而与其他扩散模式有很大的区别。正确处理模式中各参数及变量的相互关系才能客观地反映污染物对环境影响的结果。本研究通过对熏烟模式的非定常性和各参数、变量相互关系的分析 ,提出了正确使用该模式的方法 相似文献
7.
8.
The printed circuit board (PCB) manufacturers face several problems regarding the waste they generate. In Austria, a detailed study for waste minimization was carried out with three PCB manufacturers and one electroplating company. In this project a lot of ecologically and economically effective options were found and implemented. The ecological evaluation of processes is still an unsolved problem. Several evaluation models are tested on selected processes of the project. 相似文献
9.
控制和降低城市上空SO2的环境浓度对于改善城市环境,促进城市生态的良性循环具有十分重要的意义。本文从上海市绿化三维量分布模型、与SO2浓度分布模型的相关分析入手,以季节变化作为对比因子,讨论了城市绿化植物群的数量及分布对城市上空SO2浓度分布的宏观影响;并据此提出了可有效地控制城市上空SO2浓度的绿地建设的基本原则。 相似文献
10.
IntroductionCleaningthefineparticlesinhightemperature (450℃ -950℃ )andhighpressureconditioncanenhancethethermalefficiencyofcleancoaltechnologiessuchasIGCCorPFBC .Rigidceramicfiltersofavarietyofstructuresareunderdevelopmentinprogramsaroundtheworld ,whichcanfi… 相似文献