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1.
Glycine(Gly) is ubiquitous in the atmosphere and plays a vital role in new particle formation(NPF).However,the potential mechanism of its on sulfuric acid(SA)-ammonia(A)clusters formation under various atmospheric conditions is still ambiguous.Herein,a(Gly)_x·(SA)_y·(A)_z(z≤x+y≤3) multicomponent system was investigated by using density functional theory(DFT) combined with Atmospheric Cluster Dynamics Code(ACDC) at different temperatures and precursor concentrations.The results show that Gly,with one carboxyl(-COOH) and one amine(-NH_2) group,can interact strongly with SA and A in two directions through hydrogen bonds or proton transfer.Within the relevant range of atmospheric concentrations,Gly can enhance the formation rate of SA-A-based clusters,especially at low temperature,low [SA],and median [A].The enhancement(R) of Gly on NPF can be up to 340 at T=218.15 K,[SA]=10~4,[A]=10~9,and [Gly]=10~7 molecules/cm~3.In addition,the main growth paths of clusters show that Gly molecules participate into cluster formation in the initial stage and eventually leave the cluster by evaporation in subsequent cluster growth at low [Gly],it acts as an important "transporter" to connect the smaller and larger cluster.With the increase of [Gly],it acts as a "participator" directly participating in NPF. 相似文献
2.
Ozone (O3), as a harmful air pollutant, has been of wide concern. Safe, efficient, and economical O3 removal methods urgently need to be developed. Catalytic decomposition is the most promising method for O3 removal, especially at room temperature or even subzero temperatures. Great efforts have been made to develop high-efficiency catalysts for O3 decomposition that can operate at low temperatures, high space velocity and high humidity. First, this review describes the general reaction mechanism of O3 decomposition on noble metal and transition metal oxide catalysts. Then, progress on the O3 decomposition performance of various catalysts in the past 30 years is summarized in detail. The main focus is the O3 decomposition performance of manganese oxides, which are divided into supported manganese oxides and non-supported manganese oxides. Methods to improve the activity, stability, and humidity resistance of manganese oxide catalysts for O3 decomposition are also summarized. The deactivation mechanisms of manganese oxides under dry and humid conditions are discussed. The O3 decomposition performance of monolithic catalysts is also summarized from the perspective of industrial applications. Finally, the future development directions and prospects of O3 catalytic decomposition technology are put forward. 相似文献
3.
Although the process of documenting compliance with NEPA (the National Environmental Policy Act) requires no drastic revisions, it can be managed more rigorously. Suggestions for revision can be grouped under five major steps: 1) getting a complete proposal from the applicant; 2) getting the decision-making process onto the right decision-making path; 3) modifying the applicant's proposal 4) going down a shorter path through the EA/FONSI (environmental assessment and finding of no significant impact) or through categorical exclusion review; and 5) going down the longer path through the EIS. Step 2 is perhaps the most critical, because there a decision must be made whether to write an EA/FONSI or an EIS, on the basis of whether the proposal would “significantly affect … the … environment.” In the past, this decision has not always been made promptly or rigorously. Accordingly, we suggest that the agency responsible for NEPA compliance should develop a system (a “black box”), consisting of a core group of specialists working with an interdisciplinary team, using sophisticated techniques for modeling impacts and directing both their research and their writing according to the concept of significance. By determining more efficiently and reliably whether the impacts of a proposal would be significant, such an approach would improve management of the total process. 相似文献
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综述了我国的餐饮泔水油及废油脂资源浪费、破坏环境现状,对比介绍了新工艺显著的经济及环保效益。 相似文献
6.
浦东新区城市生态问题探析 总被引:3,自引:0,他引:3
以浦东新区为个案,提出了城市开发建设较为突出的城市平衡发展、河流治理、景观规划等方面的城市生态问题,并阐述了解决方法和对策。掌握并运用生态学原理,对于城市建设和管理具有重要意义。 相似文献
7.
妨碍国有工业企业推行清洁生产的几个问题 总被引:1,自引:0,他引:1
分析不利于国有工业企业推行清洁生产的六方面问题:认识偏差,缺乏激励机制,缺乏足够的资金,技改中新技术含量低,缺乏人才和政府执行力度不够,结合实际情况初步探讨解决办法。 相似文献
8.
污水处理的新技术与新发展 总被引:18,自引:0,他引:18
介绍我国对水污染控制认识的发展和深化,阐述了污水生物处理方面的研究和新进展,包括在微生物方面的研究和新反应器、新工艺的发展。同时,讨论了新型、高效化学混凝剂和絮凝剂的开发成功,使化学法用于城市污水的处理成为可能。并提出任何一种新的处理工艺和反应器都各有其优缺点和适用条件,不能认为某一种就是最好,最先进的,可以无条件适用各种情况的。 相似文献
9.
重视环境保护规划 ,严把项目引进关 ,控制乡镇工业污染 ,增大环境保护投入 ,完善基础设施 ,严格环境管理是实现苏州新区经济与环境协调发展的主导因素。 相似文献
10.
论深入广泛推行清洁生产 总被引:2,自引:0,他引:2
在全面分析了国内推行清洁生产现状的基础上,根据中国的工业和资源特点,阐述了推行清洁生产的必要必,现时,从技术和管理两方面指出了中国推行清洁生产的巨大潜力,最后,有针对性地提出了深入广泛推行清洁生产的4条措施:(1)加快完善清洁生产政策,(2)深入实施清洁生产审计,(3)加强清洁生产技术的理论研究,(4)积极在中小企业中广泛推广清洁生产。 相似文献