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Vikram J. Kaku Michel C. Boufadel Albert D. Venosa James Weaver 《Environmental Fluid Mechanics》2006,6(4):385-406
The evaluation of dispersant effectiveness used for oil spills is commonly done using tests conducted in laboratory flasks.
We used a Hot Wire Anemometer (HWA) to characterize mixing dynamics in the Swirling Flask (SF) and the Baffled Flask (BF),
the latter is being considered by the EPA to replace the prior to test dispersant effectiveness in the laboratory. Five rotation
speeds of the orbital shaker carrying the flasks were considered, Ω = 50, 100, 150, 175 and 200 rpm. The radial and azimuthal
water speeds were measured for each Ω. It was found that the flow in the SF is, in general, two-dimensional changing from
horizontal at low Ω to axi-symmetric at high Ω. The flow in the BF appeared to be three-dimensional at all rotation speeds.
This indicates that the BF is more suitable for representing the (inherently) 3-D flow at sea. In the SF, the speeds and energy
dissipation rates ɛ increased gradually as the rotation speed increased. Those in the BF increased sharply at rotation speeds
greater than 150 rpm. At 200 rpm, the Kolmogorov scale (i.e., size of smallest eddies) was about 250 and 50 μm in the SF and
BF, respectively. Noting that the observed droplet sizes of dispersed oils range from 50 to 400 μm (hence most of it is less
than 250 μm), one concludes that the mixing in the SF (even at 200 rpm) is not representative of the vigorous mixing occurring
at sea. 相似文献
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Madiha F.M. Farghaly Salah M.A.D. Zayed Soliman M. Soliman 《Journal of environmental science and health. Part. B》2013,48(7):575-581
Deltamethrin [(S)-cyano-3-phenoxybenzyl-cis-(1R,3R)-2,2-dimethyl) cyclo–propane carboxylate),1] labelled at gem-dimethyl groups of the cyclopropane ring was applied on two Egyptian soils at a level of 10 mg/kg soil for a laboratory incubation experiment under aerobic and anaerobic conditions. A steady decrease of soil extractable14C-residues, accompanied by a corresponding increase of non- extractable bound 14C-residues was observed over a 90-day incubation period. The percentage of evolved 14CO2 increased with time under aerobic and anaerobic conditions in both soils. The effect of deltamethrin on soil microorganisms as well as the counter effect of microorganisms on the insecticide was also investigated. As the incubation period increased, the inhibitory effect of the insecticide on the microorganisms decreased and the evolution of carbon dioxide depended on the applied dose. The nature of soil methanol soluble residues was determined by chromatographic analysis which revealed the presence of the parent insecticide as the main product in addition to four metabolites: 3-(2′,2′-dibromovinyl)-2,2-dimethylcyclopropane carboxylic acid (II); 3-phenoxybenzaldehyde (III); 3-phenoxybenzoic acid (IV); 3-phenoxybenzyl alcohol (V). 相似文献
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