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1.
絮凝法处理纸浆漂白废水的研究 总被引:4,自引:0,他引:4
研究了无机絮凝剂PAC,PSA,PES,MgCl2,CaO及其与有机高分子絮凝剂CGA复全使用对两种不同工艺漂白废水的混凝处理特性,结果表明,水质1CODcr,AOX去除率分别为63.2%,45.3%,水质2CODcr,AOX去除率达73.1¥%,53.4%。化钙与碳酸钠具有相同的降解AOX能力,硫离子在中性pH条件下可显著提高AOX的去除率。 相似文献
2.
Adsorbable organic halogens(AOX) are a general indicator for the total amount of compounds containing organically bonded halogens. AOX concentrations and components were investigated along the wastewater treatment process in four large-scale pharmaceutical factories of China, and genotoxicity based on the SOS/umu test was also evaluated. The results showed that AOX concentrations in wastewater of four factories ranged from 4.6 to 619.4 mg/L, which were high but greatly different owing to differences in the raw materials and products. The wastewater treatment process removed 50.0%–89.9% of AOX, leaving 1.3–302.5 mg/L AOX in the effluents. Genotoxicity levels ranged between 2.1 and 68.0 μg 4-NQO/L in the raw wastewater and decreased to 1.2–41.2 μg 4-NQO/L in the effluents of the wastewater treatment plants(WWTPs). One of the main products of factory I, ciprofloxacin, was identified as the predominant contributor to its genotoxicity. However, for the other three factories, no significant relationship was observed between genotoxicity and detected AOX compounds. 相似文献
3.
用Fenton氧化处理合成制药企业活性污泥混合液,考察了不同Fe~(2+)、H_2O_2投加量和不同反应时间下污泥与上清液中AOX(可吸附有机卤代物)的去除效果,优化了反应条件,探讨了氧化机制.结果表明,Fenton氧化的最佳条件为H_2O_2投加量0.90 mol·L~(-1),Fe~(2+)投加量0.045 mol·L~(-1)[物质的量比为:n(Fe~(2+))∶n(H_2O_2)=1∶20],反应2 h,污泥和上清液中AOX可分别去除70.7%和78.5%.GC-MS分析结果显示,污泥中含有11种有机卤代物,Fenton氧化后有8种不再检出;3种仍有检出,但浓度有所降低,去除率约为40%~50%.与此同时,污泥中对二甲苯、邻苯二甲酸二异丁酯等非有机卤代物类有毒有害有机物也得到有效去除. 相似文献
4.
AOX漂白废水对黑鲷鱼卵及仔鱼的毒性效应 总被引:8,自引:0,他引:8
用含AOX的造纸漂白废水对人工养殖的黑鲷鱼卵和早期仔鱼进行了毒性实验.结果表明:对于AOX漂白废水的毒性,黑鲷鱼卵胚胎阶段比早期仔鱼阶段更为敏感.高浓度的AOX漂白废水对鱼卵孵化产生一定的抑制作用,对仔鱼产生尾部畸形和致死现象,鱼卵孵化的EC50和95%置信区间分别为0.018和0~0.087 mL/mL;仔鱼72 h LC50和96h LC50分别为0.557和0.774 mL/mL,72 h的LOEC和NOEC分别为0.032和0.001 mL/mL,96 h的LOEC和NOEC分别为0.003和0.001 mL/mL.表明仔鱼对AOX漂白废水的毒性敏感性随着时间的推移而逐渐减弱. 相似文献
5.
Jan Bernd Barhorst Roland Kubiak 《Environmental science and pollution research international》2009,16(5):582-589
Background, aim and scope The use of sodium hypochlorite (HYP) in viticulture results in effluents which are contaminated with halogenated substances.
These disinfection by-products (DBPs) can be quantified as group parameter ‘adsorbable organic halogens’ (AOX) and have not
been determined in effluents of viticulture yet. The substances that are detected as AOX are unknown. The AOX can be composed
of harmless substances, but even toxic contaminants. Thus, it is impossible to assess ecological impacts. The aim of this
study is to determine the quantification of AOX and DBPs after the use of HYP. This will be helpful to reduce environmental
pollution by AOX.
Materials and methods The potential of HYP to generate AOX was determined in laboratory-scale experiments. Different model solutions were treated
with HYP according to disinfection processes in viticulture and conditions of AOX formation in effluents were simulated. AOX
were quantified using the flask-shaking method and identified DBPs were investigated by gas chromatography–mass spectrometry.
Results Treatment with HYP resulted in the formation of AOX. The percentage conversion of HYP to AOX was up to 11%. Most important
identified DBPs in viticulture are chloroform, dichloroacetic acid and trichloroacetaldehyde. In addition, the formation of
carbon tetrachloride (CT), 1,1,1-trichloropropanone, 2,4-dichlorobenzoic acid and 2-chloro-/2,4-dichlorophenylacetic acid
was investigated. It was demonstrated that reaction temperature, concentration of HYP and type of organic matter have important
influence on the formation of chlorinated DBPs.
Discussion The percentage conversion of HYP to AOX was similar to other published studies. Although a correlation of single compounds
and AOX is difficult, chloroform was the predominant AOX. Generation of the volatile chloroform should be avoided due to possible
adverse effects. The generation of dichloroacetic acid is of minor importance on account of biodegradation. Trichloroacetaldehyde
and 1,1,1-trichloropropanone are weak mutagens and their formation should be avoided.
Conclusions The generation of AOX and chlorinated DBPs can be minimised by reducing the concentrations of the organic materials in the
effluents. The removal of organic matter before disinfection results in a decreased formation of AOX. HYP is an effective
disinfectant; therefore, it should be used at low temperatures and concentrations to reduce the amount of AOX. If possible,
disinfection should be accomplished by the use of no chlorine-containing agents. By this means, negative influences of HYP
on the quality of wine can also be avoided.
Recommendations and perspectives Our results indicate that HYP has a high potential to form AOX in effluents of viticulture. The predominant by-products are
chloroform, dichloroacetic acid and trichloroacetaldehyde. In further research, wastewaters from a winery and the in- and
outflows of two sewage treatment plants were sampled during vintage and analysed. These results will be discussed in a following
paper. 相似文献
6.
采用土壤柱试验研究了土壤渗滤对再生水中有机微污染物的去除性能。结果表明,土壤柱对再生水中的DOC、UV254、总氮和总磷有较好的去除效果,并具有较高的抗冲击负荷的能力;土壤表层10 cm厚度对DOC的去除起主要作用;UV254和AOX在土壤表层10 cm厚度降解效果不明显,随着深度增加去除率逐渐升高;液相色谱有机碳探测(LC-OCD)检测结果表明,土壤柱对溶解性有机物质的去除主要体现在对多糖物质的降解上,其次是有机酸类,对腐殖质也有一定的去除作用。 相似文献
7.
造纸工业总排水及漂白废水中AOX监测方法的研究 总被引:4,自引:0,他引:4
运用TOX测定仪对造纸工业废水及漂白废水中AOX(可吸附有机卤素)测定;水样用硝酸调pH<2后,以双根活性炭玻璃填充柱连续吸附;将吸附有机物的活性炭在氧气流中燃烧热解、用微库仑法测定其卤化氢.样品前处理比现行活性炭振荡吸附法样品及试剂用量少、快速、重现性好.方法测定浓度下限为3.73μg/L. 相似文献
8.
9.
Yukio Noma Sayuri Yamane Akiko Kida 《Journal of Material Cycles and Waste Management》2001,3(2):126-134
Adsorbable organic halides (AOX) and AOX formation potential (AOXFP) were investigated in 46 landfill lea-chates as potentially
toxic parameters. AOX in landfill leachate was within the range <10–2200 μg Cl/l, and AOXFP was within 51–15 000 μg Cl/l.
AOX and AOXFP correlated with chemical oxygen demand (COD). AOX discharge from closed landfills was generally lower than that
from operating landfills. The molar ratio of AOXFP/total organic carbon (TOC) suggested that organic compounds in a leachate
have a double bond every 15–190 carbons under the supposition that one chlorine would add to one double bond. The five landfills
discharging high-level AOXFP (>4000 μg Cl/l) were all landfills where sludge had been dumped. The removal efficiencies of
three parameters through leachate treatment processes were as follows: polychlorinated dibenzo-dioxins/dibenzo-furans (PCDDs/DFs)
> TOC > AOX. PCDDs/DFs were substantially removed at p.p.t. levels, while AOX was hardly removed at relatively low levels.
Received: February 14, 2000 / Accepted: January 9, 2001 相似文献
10.