Synergistic effects of Cu species and acidity of Cu-ZSM-5 on catalytic performance for selective catalytic oxidation of n-butylamine

In this work, a series of Cu-ZSM-5 catalysts with different SiO₂/Al₂O₃ ratios (25, 50, 100 and 200) were synthesized and investigated in n-butylamine catalytic degradation. The n-butylamine can be completely catalytic degradation at 350°C over all Cu-ZSM-5 catalysts. Moreover, Cu-ZSM-5 (25) exhibited the highest selectivity to N₂, exceeding 90% at 350°C. These samples were investigated in detail by several characterizations to illuminate the dependence of the catalytic performance on redox properties, Cu species, and acidity. The characterization results proved that the redox properties and chemisorption oxygen primarily affect n-butylamine conversion. N₂ selectivity was impacted by the Brønsted acidity and the isolated Cu²⁺ species. Meanwhile, the surface acid sites over Cu-ZSM-5 catalysts could influence the formation of Cu species. Furthermore, in situ diffuse reflectance infrared Fourier transform spectra was adopted to explore the reaction mechanism. The Cu-ZSM-5 catalysts are the most prospective catalysts for nitrogen-containing volatile organic compounds removal, and the results in this study could provide new insights into catalysts design for VOC catalytic oxidation.     

南京市建筑施工环境噪声的管理与对策

针对建筑施工环境噪声扰民问题投诉居高不下，提出环境监理部门要积极宣传环保法律法规，规范举报工作，认真受理投诉，以取得市民的理解与支持；严格审批夜间建筑施工，加大监管力度，做好对夜间施工现场的核查；加强行风建设，通过内强素质，提高自身的业务水平，监督与服务并重；拓展工作思路，加强与建工、公安、市容、市政供电等部门的合作，共同解决噪声扰民问题。     

Water Quality Evaluation and Trend Analysis in Selected Watersheds of the Atlantic Region of Canada

Water quality indices (WQIs) have been developed to assess the suitability of water for a variety of uses. These indices reflect the status of water quality in lakes, streams, rivers, and reservoirs. The concept of WQIs is based on a comparison of the concentration of contaminants with the respective environmental standards. The number, frequency, and magnitude by which the environmental standards for specific variables are not met in a given time period are reflected in WQIs. Further, the water quality trend analysis predicts the behavior of the water quality parameters and overall water quality in the time domain. In this paper, the concept of WQI was applied to three selected watersheds of Atlantic region: the Mersey River, the Point Wolfe River, and the Dunk River sites. To have robust study, two different water quality indices are used: Canadian Water Quality Index (CWQI), and British Columbia Water Quality Index (BWQI). The complete study was conducted in two steps. The first step was to organize and process the data into a format compatible with WQI analysis. After processing the input data, the WQI was calculated. The second step outlined in the paper discusses detailed trend analysis using linear and quadratic models for all the three sites. As per the 25 years trend analysis, overall water quality for agriculture use observed an improving trend at all the three sites studied. Water quality for raw water used for drinking (prior to treatment) and aquatic uses has shown improving trend at Point Wolfe River. It is further observed that pH, SO₄, and NO₃ concentrations are improving at Dunk River, Mersey River, and Point Wolfe River sites. To ascertain the reliability and significance of the trend analysis, a detailed error analysis and parametric significance tests were also conducted It was observed that for most of the sites and water uses quadratic trend models were a better fit than the linear models.     

建设项目审批数据管理系统的设计与实现

本系统根据葫芦岛市环境保护的需要,整合各种环境保护建设项目审批数据,建立Oracle数据仓库,利用PowerBuilder技术完成对环境保护建设项目数据的管理、统计与发布。     

溧阳市国家级生态示范区建设工作初探

综述了溧阳市创建国家级生态示范区的背景、依据、基础条件、创建的目标和技术路线，介绍了示范区建设的内容和具有特点的生态经济发展模式。     

BP网络应用于大气环境监测点的优选

为了对大气环境监测点进行优化选择 ,以大气质量分级标准为训练样本 ,构造BP网络进行训练 ,用训练好的BP网络对某地的大气环境监测采样点进行了优选 ,并与物元分析法优选结果进行比较。结果表明 ,BP网络用于环境测点优选具有较好的客观性和应用性     

建筑施工噪声污染及其防治对策

对建筑施工噪声主要污染源的组成进行了分析和评述 ,并提出了相应的防治措施     

公众参与在建设项目环境影响评价中的重要性

通过对公众参与建设项目环境影响评价进行简要分析,针对公众参与“环境影响评价”工作中存在的问题提出相应的对策与建议。进一步探索如何提高“环境影响评价”公众参与的有效性,由此阐述公众参与在建设项目环境影响评价中的重要性。     

潜在危害性指数法在筛选污染因子中的应用

介绍了潜在危害性指数法的基本原理和计算公式，通过某大型化工企业的实例，提出了应用的要求，并筛选出了企业的９项主要的环境监测因子。     

Optimizing the atmospheric sampling sites using fuzzy mathematic methods

A new approach applying fuzzy mathematic theorems, including the Primary Matrix Element Theorem and the Fisher Classification Method, was established to solve the optimization problem of atmospheric environmental sampling sites. According to its basis, an application in the optimization of sampling sites in the atmospheric environmental monitoring was discussed. The method was proven to be suitable and effective. The results were admitted and applied by the Environmental Protection Bureau (EPB) of many cities of China. A set of computer software of this approach was also comuletelv comniled and used.