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排序方式: 共有422条查询结果,搜索用时 15 毫秒
1.
Xin Xing Na Li Jie Cheng Yonggang Sun Zhongshen Zhang Xin Zhang Zhengping Hao 《环境科学学报(英文版)》2020,32(10):55-63
In this work, a series of Cu-ZSM-5 catalysts with different SiO2/Al2O3 ratios (25, 50, 100 and 200) were synthesized and investigated in n-butylamine catalytic degradation. The n-butylamine can be completely catalytic degradation at 350°C over all Cu-ZSM-5 catalysts. Moreover, Cu-ZSM-5 (25) exhibited the highest selectivity to N2, exceeding 90% at 350°C. These samples were investigated in detail by several characterizations to illuminate the dependence of the catalytic performance on redox properties, Cu species, and acidity. The characterization results proved that the redox properties and chemisorption oxygen primarily affect n-butylamine conversion. N2 selectivity was impacted by the Brønsted acidity and the isolated Cu2+ species. Meanwhile, the surface acid sites over Cu-ZSM-5 catalysts could influence the formation of Cu species. Furthermore, in situ diffuse reflectance infrared Fourier transform spectra was adopted to explore the reaction mechanism. The Cu-ZSM-5 catalysts are the most prospective catalysts for nitrogen-containing volatile organic compounds removal, and the results in this study could provide new insights into catalysts design for VOC catalytic oxidation. 相似文献
2.
Water quality indices (WQIs) have been developed to assess the suitability of water for a variety of uses. These indices reflect the status of water quality in lakes, streams, rivers, and reservoirs. The concept of WQIs is based on a comparison of the concentration of contaminants with the respective environmental standards. The number, frequency, and magnitude by which the environmental standards for specific variables are not met in a given time period are reflected in WQIs. Further, the water quality trend analysis predicts the behavior of the water quality parameters and overall water quality in the time domain. In this paper, the concept of WQI was applied to three selected watersheds of Atlantic region: the Mersey River, the Point Wolfe River, and the Dunk River sites. To have robust study, two different water quality indices are used: Canadian Water Quality Index (CWQI), and British Columbia Water Quality Index (BWQI). The complete study was conducted in two steps. The first step was to organize and process the data into a format compatible with WQI analysis. After processing the input data, the WQI was calculated. The second step outlined in the paper discusses detailed trend analysis using linear and quadratic models for all the three sites. As per the 25 years trend analysis, overall water quality for agriculture use observed an improving trend at all the three sites studied. Water quality for raw water used for drinking (prior to treatment) and aquatic uses has shown improving trend at Point Wolfe River. It is further observed that pH, SO4, and NO3 concentrations are improving at Dunk River, Mersey River, and Point Wolfe River sites. To ascertain the reliability and significance of the trend analysis, a detailed error analysis and parametric significance tests were also conducted It was observed that for most of the sites and water uses quadratic trend models were a better fit than the linear models. 相似文献
3.
曲霉对水中重金属的吸附去除 总被引:15,自引:0,他引:15
利用2种曲霉A.sojae M146和A.oryzae M149的菌体,作为吸附剂对水中Pb^2+和Cd^2 进行去除实验。结果表明,曲霉菌体的最佳培养时间为72h,吸附的最佳pH为5.5、温度为30℃、时间为1h。在最佳实验条件下,A.sojae M146对Pb^2 和Cd^2 的吸附率,分别为69.76%和72.28%;A.oryzae M149对Pb^2 和Cd^2 的吸附率,分别为60.64%和81.34%。使用稀碱溶液对曲霉菌体进行浸泡预处理后,可提高对重金属的吸附去除效果;而使用稀释、乙醇水溶液以及蒸馏水对菌体浸泡后,明显降低了重金属的去除效果。Na2CO3和EDTA溶液,可以有效地将重金属从曲霉体上解吸下来,从而达到重复利用菌体作为吸附剂的目的。 相似文献
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A new approach applying fuzzy mathematic theorems, including the Primary Matrix Element Theorem and the Fisher Classification Method, was established to solve the optimization problem of atmospheric environmental sampling sites. According to its basis, an application in the optimization of sampling sites in the atmospheric environmental monitoring was discussed. The method was proven to be suitable and effective. The results were admitted and applied by the Environmental Protection Bureau (EPB) of many cities of China. A set of computer software of this approach was also comuletelv comniled and used. 相似文献
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Major mining companies have recently embraced the sustainable development paradigm, in seeking to improve their competitiveness and increase shareholder returns. Successful mine closure is one important element of this process. Improved performance in this area is essential if surrounding communities are to see mining companies as responsible corporate and social partners.
In Indonesia, the new approach has coincided with the development of specific mine closure legislation. To facilitate the legislation, a consortium of mining companies joined to form the Industry Mine Closure Steering Committee. This Committee has lobbied the Government, actively negotiating to incorporate sustainable development ideals and practices into the new legislation. The Committee's aim has been to foster continued development of the mining industry, while taking account of variation in environmental, social and community conditions. In describing the process, this article seeks to provide guidance for the development of mine closure legislation in other nations. 相似文献
In Indonesia, the new approach has coincided with the development of specific mine closure legislation. To facilitate the legislation, a consortium of mining companies joined to form the Industry Mine Closure Steering Committee. This Committee has lobbied the Government, actively negotiating to incorporate sustainable development ideals and practices into the new legislation. The Committee's aim has been to foster continued development of the mining industry, while taking account of variation in environmental, social and community conditions. In describing the process, this article seeks to provide guidance for the development of mine closure legislation in other nations. 相似文献
9.
矿井通风系统模糊可靠性研究 总被引:2,自引:1,他引:2
定义模糊可靠度为一个服从正态分布的模糊数,并以模糊数作为通风系统的各风路可靠度,进而提出了矿井通风系统的模糊可靠度计算方法。同时在置信水平上,确定矿井通风系统的普通可靠度置信区间。若=1,则模糊可靠度计算转化为可靠度计算。 相似文献
10.
采掘诱发地震的成因及对策 总被引:14,自引:4,他引:14
根据煤或岩体的赋存特征及采动后的受力特点,将采矿及掘进等工程进行过程中诱发的地震灾害分为三类,即完整煤岩体受压应力作用的失稳、顶底板受拉应力型地震及断层走滑受剪型诱发地震。文章在分别分析其成因的基础上,研究了采矿诱发三种类型地震的发生条件,提出了防治发生诱发地震的对策。 相似文献