石墨炉原子吸收分光光度法测地面水中的铍

介绍了用石墨炉原子吸收分光光度计测定地面水中的铍的方法的建立     

内电解法预处理甲基氯化物生产废水的研究

用内电解法预处理有机磷农药中间体甲基氯化物生产废水，结果表明是可行的，废水CODcr，有机磷，硫化物的去除率分别达到62.43%，60.62%，76.37%，出水的BOD5／CODcr由0.107上升至0.302，为后续的生化处理创造了良好的条件。实验确定的操作条件为铁碳比铁碳比2、废水pH值5.5,反应温度＞50℃，停留时间＞7h，CaO用量200mg/L。     

高浓度废水预处理

从分析冲击炼油污水处理的原因出发，阐述了高浓度废水预处理的重要性；重点介绍了三种好氧生物法处理技术；其中ＳＢＲ法由于工程技术日趋成熟，可优先推广应用     

土壤渗滤处理技术研究现状与进展

土壤渗滤处理技术在我国广大地区有很好的适应性和可行性,将有很好的发展前景。该文论述了土壤渗滤技术的发展历史和现状,并对近十年来该技术的实验室模拟、机理研究、具体应用实践和运行模式的优化等方面进行了概括分析与总结      

胰岛素废水处理工程设计

针对某医药公司在制取胰岛素过程中产生的高浓度废水，采用预处理（酒精回收-盐水投配-除油）-倒A2O-接触氧化-化学除磷组合工艺进行调试，其处理效果明显，出水各项指标均能达标，同时对工艺中存在的缺陷进行了分析。     

纳氏试剂比色法中样品的预处理

氨是一种无色且有强烈刺激性臭味的气体,居住区大气中有害物质最高容许浓度氨的一次限值是0．2mg／m3。本文研究了环境空气监测中氨的测定方法,分析氨的预处理对监测结果的影响。     

预处理方法对供应态LD钢超塑性压缩性能的影响

研究了国产新型冷作模具钢LD钢(7Cr7Mo3V2Si)经球化退火与循环退火后的超塑性压缩的力学特性.试验结果表明,经循环退火后的LD钢,其超塑性压缩性能优于球化退火,而且其最佳超塑性压缩的工艺参数也存在差异.     

Synthesis and evaluation of cationic flocculant P(DAC-PAPTAC-AM) for flocculation of coal chemical wastewater

In this study, a high-efficiency cationic flocculant, P(DAC-MAPTAC-AM), was successfully prepared using UV-induced polymerization technology. The monomer Acrylamide (AM): Acryloxyethyl Trimethyl ammonium chloride (DAC): methacrylamido propyl trimethyl ammonium chloride (MAPTAC) ratio, monomer concentration, photoinitiator concentration, urea content, and cationic monomer DAC:MAPTAC ratio, light time, and power of high-pressure mercury lamp were studied. The characteristic groups, characteristic diffraction peaks, and characteristic proton peaks of P(DAC-MAPTAC-AM) were confirmed by fourier transform infrared spectroscopy (FTIR), X-Ray diffraction (XRD), ¹H nuclear magnetic resonance spectrometer (¹H NMR), and scanning electron microscopy (SEM). The effects of dosage, pH value, and velocity gradient (G) value on the removal efficiencies of turbidity, COD, ammonia nitrogen, and total phenol by poly aluminum ferric chloride (PAFC), P(DAC-MAPTAC-AM), and PAFC/P(DAC-MAPTAC-AM) in the flocculation treatment of coal chemical wastewater were investigated. Results showed that the optimal conditions for the flocculation of coal chemical wastewater using P(DAC-MAPTAC-AM) alone are as follows: dosage of 8–12 mg/L, G value of 100–250 s ^? 1, and pH value of 4–8. The optimal dosage of PAFC is 90–150 mg/L with a pH of 2–12. The optimal dosage for PAFC/P(DAC-MAPTAC-AM) is as follows: PAFC dosage of 90–150 mg/L, P(DAC-MAPTAC-AM) dosage of 8–12 mg/L, and pH range of 2–6. When P(DAC-MAPTAC-AM) was used alone, the optimal removal efficiencies of turbidity, COD, ammonia nitrogen, and total phenol were 81.0%, 35.0%, 75.0%, and 80.3%, respectively. PAFC has good tolerance to wastewater pH and good pH buffering. Thus, the flocculation treatment of coal chemical wastewater using the PAFC/P(DAC-MAPTAC-AM) compound also exhibits excellent resistance and buffering capacity.     

Ultrasound and enzyme assisted biodegradation of distillery wastewater

Irradiation with ultrasound (US) and use of an enzyme (E) as pretreatment techniques were carried out to treat a complex effluent (distillery wastewater). These two techniques have been used alone as well as in combination and the efficacy of these techniques was tested by subjecting the effluent to subsequent aerobic biological oxidation (AO). When used alone, US exposure for 30 min and 2 h yielded the best COD reduction during the aerobic oxidation step (US+AO). For the enzyme when used alone, a pH value of 4.8 (corresponding to the optimum pH of the enzyme), a dose of 50 U and a pretreatment time of 24 h yielded better COD removal efficiency as compared to untreated effluent (aerobic oxidation alone). When used in combination, ultrasound followed by enzymatic pretreatment (US+E+AO) yielded the best COD removal efficiencies during aerobic oxidation as compared to the other combinations tested for the treatment of the distillery wastewater. A 4-fold increase in the initial oxidation rate was observed over the untreated batch for the integrated technique (US+E+AO). On the basis of the variation in the values of the biokinetic parameters it can be concluded that the type of pretreatment scheme affects the subsequent rate of the aerobic oxidation significantly.     

Biodiesel production from vegetable oil and waste animal fats in a pilot plant

In this study, corn oil as vegetable oil, chicken fat and fleshing oil as animal fats were used to produce methyl ester in a biodiesel pilot plant. The FFA level of the corn oil was below 1% while those of animal fats were too high to produce biodiesel via base catalyst. Therefore, it was needed to perform pretreatment reaction for the animal fats. For this aim, sulfuric acid was used as catalyst and methanol was used as alcohol in the pretreatment reactions. After reducing the FFA level of the animal fats to less than 1%, the transesterification reaction was completed with alkaline catalyst. Due to low FFA content of corn oil, it was directly subjected to transesterification. Potassium hydroxide was used as catalyst and methanol was used as alcohol for transesterification reactions. The fuel properties of methyl esters produced in the biodiesel pilot plant were characterized and compared to EN 14214 and ASTM D6751 biodiesel standards. According to the results, ester yield values of animal fat methyl esters were slightly lower than that of the corn oil methyl ester (COME). The production cost of COME was higher than those of animal fat methyl esters due to being high cost biodiesel feedstock. The fuel properties of produced methyl esters were close to each other. Especially, the sulfur content and cold flow properties of the COME were lower than those of animal fat methyl esters. The measured fuel properties of all produced methyl esters met ASTM D6751 (S500) biodiesel fuel standards.