全文获取类型
收费全文 | 7588篇 |
免费 | 1032篇 |
国内免费 | 4520篇 |
专业分类
安全科学 | 769篇 |
废物处理 | 325篇 |
环保管理 | 1005篇 |
综合类 | 6879篇 |
基础理论 | 1429篇 |
环境理论 | 1篇 |
污染及防治 | 1902篇 |
评价与监测 | 535篇 |
社会与环境 | 207篇 |
灾害及防治 | 88篇 |
出版年
2024年 | 42篇 |
2023年 | 222篇 |
2022年 | 351篇 |
2021年 | 450篇 |
2020年 | 383篇 |
2019年 | 414篇 |
2018年 | 447篇 |
2017年 | 537篇 |
2016年 | 619篇 |
2015年 | 626篇 |
2014年 | 640篇 |
2013年 | 797篇 |
2012年 | 852篇 |
2011年 | 815篇 |
2010年 | 616篇 |
2009年 | 680篇 |
2008年 | 487篇 |
2007年 | 629篇 |
2006年 | 591篇 |
2005年 | 446篇 |
2004年 | 345篇 |
2003年 | 362篇 |
2002年 | 295篇 |
2001年 | 239篇 |
2000年 | 221篇 |
1999年 | 201篇 |
1998年 | 150篇 |
1997年 | 130篇 |
1996年 | 110篇 |
1995年 | 100篇 |
1994年 | 74篇 |
1993年 | 58篇 |
1992年 | 39篇 |
1991年 | 38篇 |
1990年 | 19篇 |
1989年 | 16篇 |
1988年 | 13篇 |
1987年 | 21篇 |
1986年 | 4篇 |
1985年 | 7篇 |
1983年 | 3篇 |
1982年 | 5篇 |
1981年 | 7篇 |
1980年 | 6篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1977年 | 6篇 |
1972年 | 2篇 |
1971年 | 4篇 |
1970年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 10 毫秒
1.
Background, Aim and Scope Air quality is an field of major concern in large cities. This problem has led administrations to introduce plans and regulations
to reduce pollutant emissions. The analysis of variations in the concentration of pollutants is useful when evaluating the
effectiveness of these plans. However, such an analysis cannot be undertaken using standard statistical techniques, due to
the fact that concentrations of atmospheric pollutants often exhibit a lack of normality and are autocorrelated. On the other
hand, if long-term trends of any pollutant’s emissions are to be detected, meteorological effects must be removed from the
time series analysed, due to their strong masking effects.
Materials and Methods The application of statistical methods to analyse temporal variations is illustrated using monthly carbon monoxide (CO) concentrations
observed at an urban site. The sampling site is located at a street intersection in central Valencia (Spain) with a high traffic
density. Valencia is the third largest city in Spain. It is a typical Mediterranean city in terms of its urban structure and
climatology. The sampling site started operation in January 1994 and monitored CO ground level concentrations until February
2002. Its geographic coordinates are W0°22′52″ N39°28′05″ and its altitude is 11 m. Two nonparametric trend tests are applied.
One of these is robust against serial correlation with regards to the false rejection rate, when observations have a strong
persistence or when the sample size per month is small. A nonparametric analysis of the homogeneity of trends between seasons
is also discussed. A multiple linear regression model is used with the transformed data, including the effect of meteorological
variables. The method of generalized least squares is applied to estimate the model parameters to take into account the serial
dependence of the residuals of this model. This study also assesses temporal changes using the Kolmogorov-Zurbenko (KZ) filter.
The KZ filter has been shown to be an effective way to remove the influence of meteorological conditions on O3 and PM to examine underlying trends.
Results The nonparametric tests indicate a decreasing, significant trend in the sampled site. The application of the linear model
yields a significant decrease every twelve months of 15.8% for the average monthly CO concentration. The 95% confidence interval
for the trend ranges from 13.9% to 17.7%. The seasonal cycle also provides significant results. There are no differences in
trends throughout the months. The percentage of CO variance explained by the linear model is 90.3%. The KZ filter separates
out long, short-term and seasonal variations in the CO series. The estimated, significant, long-term trend every year results
in 10.3% with this method. The 95% confidence interval ranges from 8.8% to 11.9%. This approach explains 89.9% of the CO temporal
variations.
Discussion The differences between the linear model and KZ filter trend estimations are due to the fact that the KZ filter performs the
analysis on the smoothed data rather than the original data. In the KZ filter trend estimation, the effect of meteorological
conditions has been removed. The CO short-term componentis attributable to weather and short-term fluctuations in emissions.
There is a significant seasonal cycle. This component is a result of changes in the traffic, the yearly meteorological cycle
and the interactions between these two factors. There are peaks during the autumn and winter months, which have more traffic
density in the sampled site. There is a minimum during the month of August, reflecting the very low level of vehicle emissions
which is a direct consequence of the holiday period.
Conclusions The significant, decreasing trend implies to a certain extent that the urban environment in the area is improving. This trend
results from changes in overall emissions, pollutant transport, climate, policy and economics. It is also due to the effect
of introducing reformulated gasoline. The additives enable vehicles to burn fuel with a higher air/fuel ratio, thereby lowering
the emission of CO. The KZ filter has been the most effective method to separate the CO series components and to obtain an
estimate of the long-term trend due to changes in emissions, removing the effect of meteorological conditions.
Recommendations and Perspectives Air quality managers and policy-makers must understand the link between climate and pollutants to select optimal pollutant
reduction strategies and avoid exceeding emission directives. This paper analyses eight years of ambient CO data at a site
with a high traffic density, and provides results that are useful for decision-making. The assessment of long-term changes
in air pollutants to evaluate reduction strategies has to be done while taking into account meteorological variability 相似文献
2.
3.
Ten out of the 12 new EU members, used to belong to the so-called “former eastern block”, with a post WWII environmental policy radically different from the tendencies followed in Western Europe. The lack of conservation regulations has resulted in a rather harmful industrialization, regarding natural resources and environmental quality. While air pollution transfer is a phenomenon of transboundary level, there is a particular interest in examining the contribution of the new EU member states to the environmental pressure faced by the older member states and vice versa. The current study utilises the official data for almost 20 years published by the European Monitoring and Evaluation Program concerning the transboundary transfer of NOx and SO2 in order to analyse the situation and discuss the present and future environmental policy regarding air pollution. 相似文献
4.
复合氧化物汽车尾气净化催化剂抗SO2中毒机理研究 总被引:1,自引:0,他引:1
复合氧化物催化剂(ASC)具有较高的活性和良好的抗SO_2中毒性能.用IR、XPS、TPD等技术研究了该催化剂抗SO_2中毒机理,结果表明,与易失活催化剂相比,ASC经500h反应(反应气含SO_2约20ppm),其活性组分价态无显著变化,仅表面发生SO_2的化学吸附,经与约500ppm的SO_2作用20h后,发现仅有少量SO_4~(2-)形成.这是由于在ASC催化剂中添加了特殊助剂,而使催化剂活性组分得到保护的缘故. 相似文献
5.
超细煤矸石矿粉作天然橡胶补强填充剂的性能研究 总被引:3,自引:1,他引:3
以煤矸石为原料,通过超细粉碎、表面改性等深度加工,制取了一种新的橡胶补强剂,并对煤矸石作补强剂影响因素进行初步的研究,实验表明它能够取代或部分取代炭黑用作天然橡胶的补强剂。 相似文献
6.
7.
J. J. Jesudason R. H. Marchessault T. Saito 《Journal of Polymers and the Environment》1993,1(2):89-98
The synthetic analogue of a bacterially produced polyester, poly(-hydroxybutyrate) (PHB) was synthesized from racemic -butyrolactone using anin situ trimethyl aluminum-water catalyst. The polymer was fractionated into samples differing in molecular weight and isotactic diad content. The latter was closely related to degree of crystallinity. The biodegradation of these fractions were examined by monitoring mass loss over time in the presence of anAlcaligenes faecalis T1 extracellular bacterial poly(-hydroxybutyrate) depolymerase. The fraction with high isotactic diad tacticity content showed little or no degradation over a 50 hour incubation period, whereas the fraction of intermediate isotactic diad content degraded in a continuous steady fashion at a rate that was less than that for bacterial PHB. The low isotactic diad fraction underwent a rapid initial degradation, followed by no further mass loss. The presence of stereoblocks in the polymer structure of the various fractions was an influence on the degree of susceptibility towards degradation and is related to sample crystallinity. 相似文献
8.
9.
Christopher R. Ellis Jerry Champlin Heinz G. Stefan 《Journal of the American Water Resources Association》1997,33(6):1363-1374
ABSTRACT: Evidence is presented that snowmelt runoff from an urban watershed can produce density current intrusions (underflows) in a lake. Several episodes of density current intrusions are documented. Water temperatures and salinities measured near the bottom of a 10 m deep Minneapolis lake during the late winter warming periods in 1989, 1990, 1991, and 1995 show significant rapid changes which are correlated with observed higher air temperatures and snowmelt runoff. The snowmelt runoff entering this particular lake (Ryan Lake) has increased electrical conductivity, salinity, and density. The source of the salinity is the salt spread on urban streets in the winter. Heating of littoral waters in spring may also contribute to the occurrence of the sinking flows, but is clearly not the only cause. 相似文献
10.
本文介绍采用德国进口的LB9100D监测系统对80m烟囟排放的α放射性气溶胶浓度进行连续、自动监测。并与国产FJ-367,FH-463A装置进行了对比则量,两套装置的测量结果符合得较好。 相似文献