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粉末活性炭对三烯丙基异氰脲酸酯的吸附性能
引用本文:赵泽华,孙亚兵,徐建华,荣少鹏,张艳. 粉末活性炭对三烯丙基异氰脲酸酯的吸附性能[J]. 环境工程学报, 2014, 8(1): 249-253
作者姓名:赵泽华  孙亚兵  徐建华  荣少鹏  张艳
作者单位:污染控制与资源化研究国家重点实验室, 南京大学环境学院, 南京 210046;污染控制与资源化研究国家重点实验室, 南京大学环境学院, 南京 210046;中机国际工程设计研究院有限责任公司, 南京 210049;污染控制与资源化研究国家重点实验室, 南京大学环境学院, 南京 210046;污染控制与资源化研究国家重点实验室, 南京大学环境学院, 南京 210046
摘    要:用静态吸附法考察粉末活性炭对水中三烯丙基异氰脲酸酯(CAIC)的吸附行为,采用单因素分析法对活性炭吸附化工废水中TAIC的工艺条件进行研究。实验结果表明,在TAIC模拟废水中,其TAIC初始浓度为800 mg/L,pH为7,在温度为298 K、转速为150 r/min的条件下,当活性炭的投加量达到4.4 g/L,吸附反应时间为50 min时,TAIC的去除效率最高为96.17%;对于实际废水,其TAIC初始浓度为1 500 mg/L,溶液pH为3,在温度为298 K、转速为150 r/min的条件下,当活性炭投加量达到10 g/L,吸附反应时间为2 h时,TAIC的去除效率最高为46.8%。这也是由于实际废水组分复杂,其他有机物存在一定的吸附竞争机制。

关 键 词:粉末活性炭  三烯丙基异氰脲酸酯  吸附

Adsorption property of triallyl isocyanurate onto powdered activated carbon
Zhao Zehu,Sun Yabing,Xu Jianhu,Rong Shaopeng and Zhang Yan. Adsorption property of triallyl isocyanurate onto powdered activated carbon[J]. Techniques and Equipment for Environmental Pollution Control, 2014, 8(1): 249-253
Authors:Zhao Zehu  Sun Yabing  Xu Jianhu  Rong Shaopeng  Zhang Yan
Affiliation:State Key Laboratory of Pollution Control and Resourcre Reuse, School of the Environment, Nanjing University, Nanjing 210046, China;State Key Laboratory of Pollution Control and Resourcre Reuse, School of the Environment, Nanjing University, Nanjing 210046, China;China Machinery International Engineering Design & Research Institute Co., Ltd. Nanjing 210049, China;State Key Laboratory of Pollution Control and Resourcre Reuse, School of the Environment, Nanjing University, Nanjing 210046, China;State Key Laboratory of Pollution Control and Resourcre Reuse, School of the Environment, Nanjing University, Nanjing 210046, China
Abstract:Under the liquid conditions, the adsorption of triallyl isocyanurate(TAIC) on the powdered activated carbon was examined by the static adsorption method. Moreover, the process conditions of TAIC adsorption on the powdered activated carbon in chemical wastewater was studied by the univariate analysis method. The results showed that the removal efficiency of TAIC in simulated wastewater with initial concentration of 800 mg/L and pH of 7 was up to 96.17% when the temperature,rotational speed,dosage of the activated carbon and adsorption reaction time were 298 K,150 r/min,4.4 g/L and 50 min, respectively. While in practical wastewater with initial concentration of 1 500 mg/L and pH of 3, the TAIC removal efficiency was up to 46.8% when the temperature,rotational speed,dosage of the activated carbon and adsorption reaction time were 298 K,150 r/min,10 g/L and 2 h, respectively. This was due to the complicated components and competitive adsorption mechanism of other organics.
Keywords:powdered activated carbon  triallyl isocyanurate  adsorption
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