Decomposition and removal of ionic liquid in aqueous solution by hydrothermal and photocatalytic treatment |
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Authors: | Takeshi Itakura Kazumasa Hirata Masanori Aoki Ryo Sasai Hisao Yoshida Hideaki Itoh |
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Affiliation: | (1) Division of Environmental Research, EcoTopia Science Institute, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan;(2) The Nippon Synthetic Chemical Industry Co., Ltd, Oyodonaka, Kita-ku, Osaka 531-0076, Japan;(3) Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan |
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Abstract: | We demonstrated a complete decomposition method for ionic liquids (ILs; organic cation part: butyl-methyl or ethyl-methyl imidazolium, and inorganic anion part: PF6 −, BF4 − or Br−) in aqueous media by combining a hydrothermal mineralization method with a photocatalytic decomposition (PD) method. As a result, the hydrothermal treatment with Ca(OH)2 mineralizer could effectively remove the inorganic anion part, such as PF6 − or BF4 − and the PD could decompose the organic cation part effectively. Therefore, the detoxification of ILs in aqueous media was accomplished by the present method. |
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