Removement of thiocyanate from industrial wastewater by microwave-Fenton oxidation method |
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Authors: | Bai Xi and Qingzhong Shi |
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Institution: | School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, China;School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, China |
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Abstract: | The microwave radiation oxidation process, Fenton as catalytic agent, was used to remove the thiocyanate from the industrial wastewater. The effects of microwave power, radiation time, pH and the feeding in ways of catalyst on the degradation rate of synthetic wastewater were investigated using the microwave radiation oxidation process by orthogonal experiment. The results show Fenton catalyst ratio was 1:20, the microwave radiation power was 900 W, the microwave radiation time was 7 min and the value of pH was 3. Under the optimum conditions, the removal of KSCN can reach over 90%. The apparent kinetics of removal was studied, which conformed to kinetics first-class reaction. In short, for the thiocyanate from the industrial wastewater, microwave-Fenton oxidation method is feasible and effective. |
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Keywords: | microwave technology fenton reagent thiocyanate orthogonal experiment |
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