| 4-AAP光度法测定污水中挥发酚的干扰规律研究及其应用 |
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| 引用本文： | 袁存光,刘广东,冯成武,张秀义,彭力.4-AAP光度法测定污水中挥发酚的干扰规律研究及其应用[J].环境科学,1995,16(6):59-62. |
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| 作者姓名： | 袁存光 刘广东 冯成武 张秀义 彭力 |
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| 作者单位： | 石油大学炼制系, 山东东营 257062;石油大学炼制系, 山东东营 257062;石油大学炼制系, 山东东营 257062;石油大学炼制系, 山东东营 257062;中国石油天然气总公司环保处, 北京 100724 |
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| 基金项目： | 中国石油天然气总公司重点科学技术项目 |
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| 摘 要： | 矿物油(原油、机油、柴油等)、苯胺、部分金属离子及ClO-等物质对4-AAP法测定污水中的挥发酚有干扰。本文采用标加干扰物的方法研究了各种干扰物质对挥发酚测定过程中的回收率的影响规律,得到总回收率Y方程。由Y值和4-AAP法测定值CD可求得水样中挥发酚的实际含量CT(CD/Y)。混和干扰物加标拟合实验结果的相对误差<±5%。该方法测定实际水样的结果与4阶导数光谱法的结果基本吻合。本文是针对油矿区污水特点,提出的消除各种干扰挥发酚测定物质影响的研究方法。
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| 关 键 词： | 挥发酚 干扰规律 分光光度法 水质监测 污水 |
| 收稿时间： | 1995/4/28 0:00:00 |
Study on the Interference Patterns in the 4-Amino Antipyrine Photometric Determination of Volatile Phenols in Wastewater |
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| Yuan Cunguang and Peng Li.Study on the Interference Patterns in the 4-Amino Antipyrine Photometric Determination of Volatile Phenols in Wastewater[J].Chinese Journal of Environmental Science,1995,16(6):59-62. |
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| Authors: | Yuan Cunguang and Peng Li |
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| Institution: | Dept. of Chemical Engineering, University of Petroleum, Dongying 257062;Dept. of Chemical Engineering, University of Petroleum, Dongying 257062;Dept. of Chemical Engineering, University of Petroleum, Dongying 257062;Dept. of Chemical Engineering, University of Petroleum, Dongying 257062;Dept. of Environmental Protection, China Petroleum and Natural Gas Corp., Beijing 100724 |
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| Abstract: | he interference patterns with different mineral oils (crude oil,machine oil and diesel oil),aniline,some metal ions and ClO-,etc. in the 4-AAP photometric determination of volatile phenols were studied. The recovery of phenols in the presence of different amounts of interference substances was determined spearately Then,the total recovery equation Y was established. The true concentration CT of volatile phenols in wastewaterwas determined with the value CD found by 4-AAP method and the equation Y. The result from standard addition experiment with mixed interference substances shows that its relative error to the calculated value by the equation Y is below 5%. The determined result of wastewater sampleis coincident with the results determined by the derivative photometric method. This method canbe used for the determination of volatile phenols in oil field wastewater. |
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| Keywords: | volatile phenols interference patterns 4-amino antipyrine photometry |
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