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锰离子催化氧化脱除烟气中SO2的研究
引用本文:陈昭琼,童志权. 锰离子催化氧化脱除烟气中SO2的研究[J]. 环境科学, 1995, 16(3): 32-34
作者姓名:陈昭琼  童志权
作者单位:湘潭大学化工系
摘    要:为寻求价廉、高效的烟气治理技术;对Mn^2+催化氧化脱除烟气中SO2的机理及工艺进行了研究。由实验得出其最佳的pH值为5-6,Mn^2+浓度为0.06-0.13mol/L。采用石灰石中和生成的H2SO4可维持较高的吸收率,并副产石膏。与传统的石灰法相比,该法可避免结垢与堵塞,且无需副产石膏所需的氧化过程,从而降低了投资和运行费用。

关 键 词:锰离子 催化 氧化 烟气 脱硫 火电厂
收稿时间:1995-01-09

Removal of SO2 from Flue Gas by Mn2+ Catalytic Oxidation
Chen Zhaoqiong. Removal of SO2 from Flue Gas by Mn2+ Catalytic Oxidation[J]. Chinese Journal of Environmental Science, 1995, 16(3): 32-34
Authors:Chen Zhaoqiong
Affiliation:Dept. of Chem. Eng., Xiangtan Univ., Xiangtan 411105;Dept. of Chem. Eng., Xiangtan Univ., Xiangtan 411105
Abstract:n order to develop a low Price and highly efficent Process, the mechanisms and processes for removal of SO2 from flue gas by Mn2+ catalytic oxidation have been studied. The resuhs shaw that the optimum conditions Tor the processes are pH 5-6 and the Mn2+ concentration of 0. 06-0. 13 mol/L. The use of limestone to neutralize H2SO4 in the absorbing solution may keep a high absorbing efficency and prdduce the by-product gypsum. In comparison with traditional limestone method, it may avoid scaling on the walls of equipment and slugging, and may not need a oxidation process for producing gypsum. For these reasons, there is a low investment in equipment and a low operation cost.
Keywords:flue gas   desulphurization   manganese ion   catalytic oxidation.  
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