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隔膜电解法回收利用电厂锅炉EDTA清洗废水研究
引用本文:王罗春,闻人勤,丁桓如.隔膜电解法回收利用电厂锅炉EDTA清洗废水研究[J].环境工程学报,2007,1(10):46-50.
作者姓名:王罗春  闻人勤  丁桓如
作者单位:上海电力学院环境工程系,上海,200090
基金项目:上海市重点学科建设项目 , 上海教委一般项目 , 华东电网局项目
摘    要:以涂Ir/Sn钛网板作阳极,以不锈钢网板作阴极,采用隔膜电解法处理电厂锅炉EDTA清洗废水.实验结果表明,电流、阴极电解液初始pH值和Fe/EDTA摩尔比对粉末铁析出速率影响较大,粉末铁电解析出的适宜条件是电解电流为1.0 A、阴极电解液初始pH值为5.6、阴极电解液Fe/EDTA摩尔比足够高.采用隔膜电解结合反渗透膜系统处理电厂锅炉EDTA清洗废水,可同时高效回收纳米级粉末铁和EDTA.

关 键 词:电厂锅炉EDTA清洗废水  隔膜电解  电流  阴极电解液初始pH值  Fe/EDTA摩尔比  隔膜电解法  回收利用  电厂锅炉  EDTA  boiler  清洗废水  研究  electrolysis  diaphragm  power  plant  wastewater  cleaning  纳米级粉末  高效回收  系统处理  反渗透膜  结合  电解电流  适宜条件  铁电解  影响
文章编号:1673-9108(2007)10-0046-05
修稿时间:7/1/2007 12:00:00 AM

Recovery of EDTA boiler cleaning wastewater from power plant by diaphragm electrolysis
Wang Luochun,Wen Renqin and Ding Huanru.Recovery of EDTA boiler cleaning wastewater from power plant by diaphragm electrolysis[J].Techniques and Equipment for Environmental Pollution Control,2007,1(10):46-50.
Authors:Wang Luochun  Wen Renqin and Ding Huanru
Institution:Department of Environmental Engineering, Shanghai University of Electric Power,Shanghai 200090
Abstract:Recovery of EDTA boiler cleaning wastewater from power plant by diaphragm electrolysis was studied. The titanium coated with iridium/stannum oxide and stainless steel were used as the anode and cathode, respectively. The deposition speed of Fe powder was mainly influenced by current, initial catholyte pH and toolratio of Fe and EDTA. The suitable experiment condition was current of 1.0 A, initial catholyte pH of 5.6 and adequate tool-ratio of Fe and EDTA. Fe nanoparticle and EDTA could be simultaneously and high efficiently recovered by diaphragm electrolysis combining with membrane treatment system.
Keywords:EDTA boiler cleaning wastewater from power plant  diaphragm electrolysis  current  initial catholyte pH  tool-ratio of Fe and EDTA
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