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改性沸石对水体中硝酸盐的吸附机理及其残渣的资源化利用
引用本文:李小建,王德汉.改性沸石对水体中硝酸盐的吸附机理及其残渣的资源化利用[J].中国环境管理干部学院学报,2011,21(2):13-17.
作者姓名:李小建  王德汉
作者单位:1. 惠州市欣荣环境保护科技有限公司,广东惠州,516001;华南农业大学环境科学与工程系,广东广州,510642
2. 华南农业大学环境科学与工程系,广东广州,510642
基金项目:国家863计划(2001AA246023);广东省科技计划项目
摘    要:利用HDTMA改性沸石制成吸附剂,研究对水体中硝酸盐的吸附能力和机理及吸附剂残渣的资源化应用前景。结果表明:HDTMA改性沸石可增强其对硝酸盐的吸附能力。通过红外光谱和差热分析它的吸附机理,表明:改性沸石HZ4吸附有十六烷基三甲基溴化铵(HDTMA)分子;吸附剂残渣NHZ4吸附有十六烷基三甲基溴化铵(HDTMA)分子和硝酸盐。盆栽实验结果表明:吸附剂残渣NHZ4能提高玉米生物量,最大增幅为30.4%。

关 键 词:沸石  硝酸盐  吸附剂  资源化

Study on the Adsorbing Nitrate Mechanism in Water by Modified Zeolite and Its Residue's Reclamation
Li Xiaojian,Wang Dehan.Study on the Adsorbing Nitrate Mechanism in Water by Modified Zeolite and Its Residue's Reclamation[J].Journal of Environmental Management College of China,2011,21(2):13-17.
Authors:Li Xiaojian  Wang Dehan
Institution:1.Huizhou Xinrong Environmental Protection Technology Co, Ltd, Huizhou Guangzhou 516001 ; 2. Department of Environmental Science and Engineering,South China Agricultural University, Guangzhou Guangdong 510642)
Abstract:In this paper, the adsorbents of modified zeolite by Hexadecyl Trimethyl Ammonium Bromide (HDTMA) were used to study on the nitrate adsorptive capacity in water, adsorbing mechanism and the reclamation prospect of its residue. The results showed that the modified zeolite by HDTMA had high nitrate adsorptive capacity in water. The results of IR and DTA showed molecule frame for modified zeolite HZ4 and adsorbent residue NHZ4 had HDTMA, moreover, the latter had adsorbed nitrate. The adsorbent residue NHZ4 could promote maize growth and heighten its biomass to 30.4%.
Keywords:zeolite  nitrate  adsorbent  reclamation
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