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利用新复合引发体系合成P(DMDAAC-AM)共聚物
引用本文:高宝玉,卢磊,岳钦艳,王曙光.利用新复合引发体系合成P(DMDAAC-AM)共聚物[J].环境化学,2005,24(2):162-167.
作者姓名:高宝玉  卢磊  岳钦艳  王曙光
作者单位:山东大学环境科学与工程学院,济南,250100;山东大学环境科学与工程学院,济南,250100;山东大学环境科学与工程学院,济南,250100;山东大学环境科学与工程学院,济南,250100
摘    要:采用新的复合引发体系及助剂,在水溶液中合成了分子量较高而且速溶的P(DMDAAC-AM)共聚物.着重研究各种引发剂和助剂的浓度、引发及烘干温度、反应时间等因素对聚合反应的影响,得出最佳合成工艺及配方.利用IR、透射电镜和扫描电镜对产品进行分析.

关 键 词:二甲基二烯丙基氯化铵  丙烯酰胺

USING A NEW CO-INITIATOR SYSTEM TO SYNTHESIZE P(DMDAAC-AM)
GAO Bao-yu,Lu Lei,YUE Qin-yan,WANG Shu-guang.USING A NEW CO-INITIATOR SYSTEM TO SYNTHESIZE P(DMDAAC-AM)[J].Environmental Chemistry,2005,24(2):162-167.
Authors:GAO Bao-yu  Lu Lei  YUE Qin-yan  WANG Shu-guang
Abstract:P(DMDAAC-AM), a new organic polymer flocculant, was prepared in this study by radical polymerization in aqueous solution , using a new co-initiator system. The effects of the factors such as purity of monomers, initiators concentration, polymerization temperature, drying temperature, and polymerization time onproducts performance were studied. The results show that the purity of monomers has a great effect on the molecular weights of the polymers. The purer the monomers, the larger the molecular weights of the polymers. But the other factors have an optimum for the molecular weights of the polymers, respectively. The structure of the polymer and it saggregation in aqueous solution and the surface of dried product were examined by means of various instrumental analysis techniques, including IR, TEM and SEM.
Keywords:dimethyldiallyammomium chloride  acrylamide  
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