| 改性SCR催化剂对燃煤电厂烟气中汞的催化氧化研究进展 |
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| 引用本文： | 秦亚迪, 王淑娟, 禚玉群. 改性SCR催化剂对燃煤电厂烟气中汞的催化氧化研究进展[J]. 环境工程技术学报, 2018, 8(5): 539-545. doi: 10.3969/j.issn.1674-991X.2018.05.071 |
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| 作者姓名： | 秦亚迪 王淑娟 禚玉群 |
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| 作者单位： | 1. 清华大学热科学与动力工程教育部重点实验室,北京 100084;;2. 北京市盐碱及荒漠化地区生态修复与固碳工程技术研究中心,北京 100084 |
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| 摘 要： | 针对燃煤电厂烟气中的单质汞(Hg 0)氧化技术,综述了改性SCR(选择性催化还原法)催化剂对Hg 0催化氧化的研究进展,着重阐述了金属氧化物及氯化物掺杂对改性SCR催化剂催化氧化Hg 0性能的影响;探讨了改性物质、掺杂比、烟气组分、温度等对各改性SCR催化剂催化氧化Hg 0性能的影响;从掺杂元素和烟气气氛两方面综合分析了改性SCR催化剂催化氧化Hg 0的异相反应机理。结合目前研究中存在的问题,提出改性SCR催化剂今后的研究方向,并对试验手段提出建议。
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| 关 键 词： | 燃煤烟气 Hg 0 SCR催化剂 改性 催化氧化 |
| 收稿时间： | 2018-04-20 |
Progress in catalytic oxidation of elemental mercury by modified SCR catalysts |
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| QIN Yadi, WANG Shujuan, ZHUO Yuqun. Progress in catalytic oxidation of elemental mercury by modified SCR catalysts[J]. Journal of Environmental Engineering Technology, 2018, 8(5): 539-545. doi: 10.3969/j.issn.1674-991X.2018.05.071 |
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| Authors: | QIN Yadi WANG Shujuan ZHUO Yuqun |
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| Affiliation: | 1. Key Laboratory of Thermal Science and Power Engineering of the Ministry of Education, Tsinghua University, Beijing 100084, China;;2. Beijing Engineering Research Center for Ecological Restoration and Carbon Fixation of Saline-Alkaline and Desert Land, Beijing 100084, China |
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| Abstract: | Targeting the oxidation of elemental mercury (Hg 0) in the flue gas from coal-fired power plant, the research progress of the catalytic oxidation by modified selected catalytic reduction (SCR) catalysts for elemental mercury was reviewed, focusing on the influence of metal oxides or chlorides doped SCR catalysts on elemental mercury oxidation. The activity of modified SCR catalysts for elemental mercury was explored from the effects of dopant, doping ratio, flue gas components and temperature. In addition, the heterogeneous reaction mechanisms between elemental mercury and the modified SCR catalysts were analyzed synthetically with respects to doping elements and flue gas conditions. Finally, considering the current situation of coal-fired plants, the prospects of future studies on modified SCR catalyst and the relevant experimental methods were proposed. |
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| Keywords: | coal-fired flue gas elemental mercury (Hg 0< sup>) SCR catalyst modification catalytic oxidation |
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