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基于木质素磺酸钙的湿式除尘系统氢气爆炸事故控制措施研究
引用本文:郑欣,王延瞳,许开立,张博涵. 基于木质素磺酸钙的湿式除尘系统氢气爆炸事故控制措施研究[J]. 中国安全生产科学技术, 2019, 15(6): 139-143. DOI: 10.11731/j.issn.1673-193x.2019.06.022
作者姓名:郑欣  王延瞳  许开立  张博涵
作者单位:(1.东北大学 资源与土木工程学院,辽宁 沈阳 110819;2.中化节能环保控股(北京)有限公司,北京100045)
基金项目:* 基金项目: 中央高校基本科研业务费项目(N180104018);国家重点研发计划项目(2017YFC0805100)
摘    要:为了减少湿式除尘系统发生氢气爆炸事故的可能性,提出通过抑制湿式除尘系统中铝粉与水反应的方法来从本质上加以控制。选取木质素磺酸钙为抑制剂,利用研发的金属粉与水反应产生氢气测试仪进行氢气抑制实验,得出不同浓度木质素磺酸钙溶液随时间变化的抑氢曲线,表明木质素磺酸钙能较好地抑制铝粉和水反应产生氢气。使用扫描电子显微镜(Scanning Electron Microscope,SEM)和傅里叶变换红外光谱法(Fourier Transform Infrared,FTIR)对铝粉与木质素磺酸钙溶液反应后的产物进行表征,研究木质素磺酸钙的抑制机理。研究结果表明:可以将木质素磺酸钙应用到铝制品抛光打磨场所的湿式除尘系统中,从而降低氢气爆炸事故发生的可能性。

关 键 词:湿式除尘系统  氢气爆炸  木质素磺酸钙  氢气抑制

Research on control measures of hydrogen explosion accident in wet dust removal system based on calcium lignosulfonate
ZHENG Xin1,WANG Yantong2,XU Kaili1,ZHANG Bohan1. Research on control measures of hydrogen explosion accident in wet dust removal system based on calcium lignosulfonate[J]. Journal of Safety Science and Technology, 2019, 15(6): 139-143. DOI: 10.11731/j.issn.1673-193x.2019.06.022
Authors:ZHENG Xin1  WANG Yantong2  XU Kaili1  ZHANG Bohan1
Affiliation:(1. School of Resources & Civil Engineering, Northeastern University, Shenyang Liaoning 110819, China;2. SINOCHEM Energy Saving and Environmental Protection Holding (Beijing) Co., LTD., Beijing 100045, China)
Abstract:In order to reduce the possibility of hydrogen explosion accident, it was proposed to control essentially through inhibiting the reaction of aluminium powder and water in the wet dust removal system. The calcium lignosulfonate was selected as the inhibitor, and the experiments of hydrogen inhibition were carried out by using the self developed tester of hydrogen generation by the reaction of metal powder and water. The curves of hydrogen inhibition by the calcium lignosulfonate solution with different concentrations against time were obtained, which showed that the calcium lignosulfonate could inhibit the hydrogen generated by the reaction of aluminium powder and water well. The products after the reaction of aluminium powder and calcium lignosulfonate solution were characterized by using the scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) methods, and the inhibition mechanism of calcium lignosulfonate was studied. It was proved that the calcium lignosulfonate can be used in the wet dust removal system at the polishing and grinding places of aluminium product, so as to reduce the occurrence of hydrogen explosion accident.
Keywords:wet dust removal system   hydrogen explosion   calcium lignosulfonate   hydrogen inhibition
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