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吹扫捕集-GC/MS联用定性分析城镇污水处理厂难降解污染物研究
引用本文:王慧荣,梅荣武,韦彦斐,喻治平,李明智. 吹扫捕集-GC/MS联用定性分析城镇污水处理厂难降解污染物研究[J]. 环境科学与管理, 2013, 38(8): 56-60
作者姓名:王慧荣  梅荣武  韦彦斐  喻治平  李明智
作者单位:国家环境保护水污染控制工程(浙江)中心浙江省环境保护科学设计研究院水污染控制工程重点实验室,浙江杭州310011;浙江环科环境研究院有限公司,浙江杭州310011
基金项目:浙江省科技计划项目创新团队建设与人才培养,浙江省公益技术研究社会发展项目
摘    要:采用吹扫捕集-GC/MS法对浙江省某工业园区污水处理厂中残留的难降解物质进行了定性和半定量分析,分析结果有9个响应值较高的峰,通过NIST库检索,得到这9个物质在水中残留的浓度高低依次是二氯甲烷最高,其次是四氢呋喃、三氯甲烷、1,4-二氯苯、1,2-二氯乙烷、二甲氧基甲烷、五氯环丙烷、1,4-二氯-2-氟苯、N,N-二甲基苯胺。并从这几种物质的性质、用途和这个工业园区生产企业生产的产品,分析了这几种物质在这个工业园区污水中残留的原因及危害,同时提出去除这些残留物质的方法。

关 键 词:吹扫捕集-GC  MS,定性分析,难降解物质,城镇污水处理厂

Qualitative Analysis on Refractory Pollutants from Urban Sewage Treatment Plant by Purge and Trap GC-MS
Wang Huirong , Mei Rongwu , Wei Yanfei , Yu Zhiping , Li Mingzhi. Qualitative Analysis on Refractory Pollutants from Urban Sewage Treatment Plant by Purge and Trap GC-MS[J]. Environmental Science and Management, 2013, 38(8): 56-60
Authors:Wang Huirong    Mei Rongwu    Wei Yanfei    Yu Zhiping    Li Mingzhi
Affiliation:1. National Environmental Protection Water Pollution Control Engineering Center ( Zhejiang), Environmental Protection Science Design Institute of Zhejiang Province, Key Lab of Water Pollution Controlling, Hangzhou 310011, China ;2. Environmental Science Institute of Zhejiang Province Co. , Ltd. , Hangzhou 310011, China)
Abstract:This study conducted qualitative and semi - quantitative analysis on refractory pollutants from an urban sewage treatment plant in Zhejiang Province by purge and trap - GC/MS. The results show that there are nine obvious peaks. According to NIST databank, residual concentration of the nine substances in a descending order is methylene chloride, furan tetrahydro, tri- chloromethane, benzene 1,4 - dichloro, ethane 1,2 - dichloro, methane dimethoxy, cyclopropane pentachloro, 1,4 - dichloro - 2 - fluorobenzene and N, N - dimethyl aniline. This paper analyzed the causes and dangers of these residual compounds from the properties, application and the products produced by enterprises in the industry district. Some suggestions on removing these pollutions were put forward.
Keywords:purge and trap - GC - MS  qualitative analysis  refractory pollutants  urban sewage factory
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