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电催化氧化处理除草剂异噁草酮废水的效能
引用本文:魏金枝,刘峻峰,颜婉茹,张显东,张义龙.电催化氧化处理除草剂异噁草酮废水的效能[J].环境污染治理技术与设备,2014(2):587-591.
作者姓名:魏金枝  刘峻峰  颜婉茹  张显东  张义龙
作者单位:[1]哈尔滨理工大学化学与环境工程学院、绿色化工技术黑龙江省高校重点实验室,哈尔滨150040 [2]哈尔滨工业大学城市水资源与水环境国家重点实验室,哈尔滨150090
基金项目:黑龙江省教育厅科学技术研究项目(12521118)
摘    要:为有效处理含异噁草酮除草剂废水,以Sb掺杂Ti/SnO2电极为阳极,不锈钢板为阴极,采用电催化氧化技术对异噁草酮废水进行降解,研究了不同影响因素对异噁草酮去除率的影响,并分析了异噁草酮的降解效果。结果表明,当异噁草酮初始浓度为100mg/L、电流密度为20mA/cm2、电解质投加量为0.10mol/L,反应120min后,异噁草酮去除率达到94%,此时TOC去除率为57.9%,能耗为25kWh/m2,且废水的可生化性能显著提高。

关 键 词:异噁草酮  电催化氧化  去除率  可生化性

Effectiveness of electrocatalysis oxidation treatment of herbicides clomazone wastwater
Wei Jinzhi,Liu Junfeng,Yan Wanru,Zhang Xiandong,Zhang Yilong.Effectiveness of electrocatalysis oxidation treatment of herbicides clomazone wastwater[J].Techniques and Equipment for Environmental Pollution Control,2014(2):587-591.
Authors:Wei Jinzhi  Liu Junfeng  Yan Wanru  Zhang Xiandong  Zhang Yilong
Institution:1. Key Laboratory of Green Chemical Engineering and Technology of College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040, China; 2. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China)
Abstract:In order to find an effective method for treatment of clomazone wastwater, the degradation was studied by electrocatalytic oxidation, and Sb doped Ti/SnO2 electrode was used as anode and stainless steel plate as cathode. The main influencing factors and degradation effectiveness of clomazone were discussed in the study. Results showed that when the initial concentration of clomazone was 100 mg/L, current density was 20 mA/cm2 and the electrolyte dosage was 0. 10 mol/L, 94% of clomazone was removed within 120 min. Meanwhile, TOC removal rate was 57.9% , energy consumption was 25 kWh/m3 and the biodegradability of the wastewater was improved obviously.
Keywords:clomazone  electrocatalytic oxidation  removal rate  biodegradability
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