有机污染物土地生物处理过程动态规律模拟研究

应用土壤颗粒内部有机污染物屏蔽理论,说明土地生物处理过程中残余有机污染物在土壤中的滞留现象,提出描述有机污染物在土壤及相连的水环境中生物降解过程的数学模型.其中,污染物的扩散过程用Fick第二扩散定律表示,可逆的吸附和解吸过程用线性吸附等温线表示,不可逆的土壤颗粒内部屏蔽过程用假一级反应动力学方程表示,生物降解过程用Monod动力学方程表示.模型计算结果与实验结果基本拟合,表示模型基本可靠.利用该数学模型,可以定量预测有机污染物进行土地生物处理所需的时间、处理的程度及动态规律.

Modeling Research about Bioremediation of Organic Pollutants in Soil-Water-Microbes System

A new Theory,organic pollutant sequestration inside soil particles, was applied in the research in order to explain the persistence of residual chemicals in remediation sites. Based on this theory, a mathematical model which simulates organic pollutant bioremediation process in soil-water-microbes system was developed. In the model, diffusion is represented by Fick's second law, reversible sorption-desorption by a linear isotherm, irreversible sequestration by a pseudo first order kinetics, and biodegradation by Monod kinetics. Model results match successfully with experimental data. Model simulations are performed in the study. It is noteworthy that the mathematical model will be useful in quantitatively predicting the time and degradation extend of organic pollutant in remediation sites.