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LnSrCoO4对CO和C3H8的氧化性能
引用本文:杨小毛,罗来涛,钟华. LnSrCoO4对CO和C3H8的氧化性能[J]. 环境化学, 2004, 23(6): 655-658
作者姓名:杨小毛  罗来涛  钟华
作者单位:南昌大学化学系,南昌,330047;江西财经大学材料研究所,南昌,330013;南昌大学化学系,南昌,330047
摘    要:采用聚乙二醇凝胶法制备LnSrCoO4(Ln=La,Sm)复合氧化物,考察了其对CO和C3H8的氧化反应活性,并运用XRD,BET,TEM和TPD等方法对其进行了表征.结果表明:该类复合氧化物具有四方K2NiF。结构,对CO和C3H8的氧化反应具有不同的催化活性,而LaSrCo04催化活性更好.

关 键 词:LnSrCoO4  CO  C3H8  氧化

A STUDY ON PROPERTIES OF LnSrCoO4 IN CO AND C3H8 OXIDATION REACTION
YANG Xiao mao , LUO Lai tao ZHONG Hua. A STUDY ON PROPERTIES OF LnSrCoO4 IN CO AND C3H8 OXIDATION REACTION[J]. Environmental Chemistry, 2004, 23(6): 655-658
Authors:YANG Xiao mao    LUO Lai tao ZHONG Hua
Affiliation:YANG Xiao mao 1,2 LUO Lai tao 1 ZHONG Hua 1
Abstract:The perovskite like LnSrCoO 4(Ln=La,Sm)mixed oxides were prepared by the polyglycol gel method,investigated by the XRD,BET,TEM and TPD methods,and used successfully for CO and C 3H 8 oxidation.The results indicate that LnSrCoO 4 have tetragonal K 2NiF 4 structure and good oxidative activities,and the oxidative activity of LaSrCoO 4 is better than that of SmSrCoO 4.This is explained in terms of their mobile lattice oxygen,chemisorbed oxygen and content of Co 3 .
Keywords:LnSrCoO_4  CO  C_3H_8  oxidation.
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