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微分脉冲阴极溶出伏安法测定废水中痕量的氰化物
引用本文:韦进宝,魏玉珍.微分脉冲阴极溶出伏安法测定废水中痕量的氰化物[J].环境科学与技术,1989(3):13-16,22.
作者姓名:韦进宝  魏玉珍
作者单位:武汉大学环境科学系 (韦进宝),武汉大学环境科学系(魏玉珍)
摘    要:本文报导了在0.1%的乙二胺介质中,在悬汞电极上可得到一灵敏的微分脉冲阴极溶出峰电流.峰电位约为-0.21伏(相对于Ag—Agcl电极)。CN~-浓度在0.01—9.0ppm范围内,与峰电流有线性关系.其检测限为0.1ppb。不经分离,可直接用于电镀废水和其它水质中痕量氰化物的测定.

关 键 词:溶出伏安法  氰化物

Determination of Trace Cyanide In Wastwater By Differential Pulse Cathodic Stripping Voltammetry
Wei Jinpao Wei Yuzhen.Determination of Trace Cyanide In Wastwater By Differential Pulse Cathodic Stripping Voltammetry[J].Environmental Science and Technology,1989(3):13-16,22.
Authors:Wei Jinpao Wei Yuzhen
Institution:Depart.of Envron. Science Wuhaa University
Abstract:This paper reports a method for the determination of cyanide ion by differential pulse cathodic stripping voltammetry. A Sensivity peak current can be obtained in the 0.1% ethylenediamine medium. The peak potential is about-0.21v(vs. Ag-Agcl). A linear relationship between the peak current and the concentration of cyanide ion in the range of 0.01-9.0ppm isobserved. The detection limit of cyanide ion is 0.1ppb.The method can be used to determine trace of CN-in wastwater and electroplating wastc.
Keywords:Stripping Voltammetry  Cyanide
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