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负载铂的酸活化高岭土室温甲醛氧化性能
引用本文:雷春生, 朱晓峰. 负载铂的酸活化高岭土室温甲醛氧化性能[J]. 环境工程学报, 2016, 10(10): 5743-5748. doi: 10.12030/j.cjee.201505118
作者姓名:雷春生  朱晓峰
作者单位:1.常州大学环境与安全工程学院, 常州 213164
基金项目:国家自然科学基金资助项目(51208068)
摘    要:通过盐酸活化高岭土,再利用浸泡-还原法在其表面负载金属Pt颗粒,制备出甲醛氧化催化剂。通过X射线衍射(XRD)、场发射扫面电镜(FE-SEM)、透射显微镜(TEM)、氮气吸附-脱附等温线和傅里叶红外光谱(FTIR)等对催化剂进行表征测试。结果表明:酸化处理后的高岭土的比表面积增大近1倍,负载金属Pt颗粒后作为催化剂,室温氧化甲醛具有较高的催化氧化性能,甲醛初始浓度为200 mg·m-3左右,催化氧化1 h后,甲醛剩余浓度仅为50 mg·m-3。连续循环5次,催化氧化性能变化不明显,具有稳定的催化氧化活性。

关 键 词:酸活化   高岭土     甲醛   室温氧化
收稿时间:2015-09-09

Acid activation of Pt/kaoline composite catalyst preparation and room-temperature formaldehyde oxidation
LEI Chunsheng, ZHU Xiaofeng. Acid activation of Pt/kaoline composite catalyst preparation and room-temperature formaldehyde oxidation[J]. Chinese Journal of Environmental Engineering, 2016, 10(10): 5743-5748. doi: 10.12030/j.cjee.201505118
Authors:LEI Chunsheng  ZHU Xiaofeng
Affiliation:1.School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Abstract:Pt nanoparticles were loaded onto the surface of HCl-activated kaoline using a soak-reduction method. The prepared samples were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), nitrogen adsorption-desorption isotherms, and Fourier transform infrared spectroscopy (FTIR). The results showed that the surface area of kaoline was almost doubled after acid treatment.The Pt-loaded kaoline exhibited significantly enhanced catalytic activity for formaldehyde oxidation at room temperature.The concentration of formaldehyde decreased from 200 mg·m-3 to 50 mg·m-3 within one hour. Moreover, the cyclic experiments indicated negligible deactivation after five cycles, suggesting good stability and reusability in catalytic reactions.
Keywords:acid activation  kaoline  platinum  formaldehyde  oxidation at room temperature
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