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包覆型纳米零价铁活化过硫酸处理柴油污染土壤
引用本文:吴非,陈谷汎,林伟翰,张育祯,彭彦彬. 包覆型纳米零价铁活化过硫酸处理柴油污染土壤[J]. 环境科学学报, 2016, 36(7): 2589-2595
作者姓名:吴非  陈谷汎  林伟翰  张育祯  彭彦彬
作者单位:华南理工大学环境与能源学院, 广州 510006,暨南国际大学土木工程学系, 南投 54561,暨南国际大学土木工程学系, 南投 54561,暨南国际大学土木工程学系, 南投 54561,1. 华南理工大学环境与能源学院, 广州 510006;2. 东海大学环境科学与工程学系, 台中 40704
基金项目:广州珠江新星项目(No.B2140720)
摘    要:
采用Tween-20作为包覆材料对纳米零价铁(n ZVI)进行改性(T-n ZVI),并利用T-n ZVI活化过硫酸盐(PS)降解柴油,同时与未改性纳米零价铁活化过硫酸盐体系(n ZVI/PS)进行对比.结果显示,在n ZVI/PS体系中,柴油降解率随着n ZVI及PS用量的增加而增加.在T-n ZVI/PS体系中,反应90 d后,柴油最大降解率为78%.与n ZVI/PS体系相比,T-n ZVI/PS体系所有组别的柴油降解率均有所提升,但提升幅度不大.同时对T-n ZVI活化PS的机理进行了推测.

关 键 词:nZVI  过硫酸盐  柴油  土壤
收稿时间:2015-08-23
修稿时间:2015-09-28

Remediation of diesel-contaminated soil using coated nano zero valent iron/sodium peroxydisulfate system
WU Fei,CHEN Kufan,LIN Weihan,CHANG Yuchen and PENG Yenpin. Remediation of diesel-contaminated soil using coated nano zero valent iron/sodium peroxydisulfate system[J]. Acta Scientiae Circumstantiae, 2016, 36(7): 2589-2595
Authors:WU Fei  CHEN Kufan  LIN Weihan  CHANG Yuchen  PENG Yenpin
Affiliation:School of Environment and Energy, South China University of Technology, Guangzhou 510006,Department of Civil Engineering, National Chi Nan University, Nantou 54561,Department of Civil Engineering, National Chi Nan University, Nantou 54561,Department of Civil Engineering, National Chi Nan University, Nantou 54561 and 1. School of Environment and Energy, South China University of Technology, Guangzhou 510006;2. Department of Environmental Science and Engineering, Tung Hai University, Taichung 40704
Abstract:
In this study, Tween20 was chosen to coat nano zero valent iron (T-nZVI). The feasibility of remediating diesel-contaminated soil using persulfate(PS) activated by T-nZVI and nZVI was then investigated. It was observed that larger amount of T-nZVI favored PS decomposition and diesel degradation. The maximum degradation efficiency of diesel was 78% within 90 days in the T-nZVI system. Compared with the nZVI system, the degradation efficiency of diesel was slightly higher in the T-nZVI system. Possible mechanism of persulfate activation by T-nZVI was inferred based on the analysis data.
Keywords:nano zero valent iron  sodium peroxydisulfate  diesel  soil
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