| 二氧化硫与1—己烯的光化学反应动力学 |
| |
| 引用本文： | 郭海忱 杜尧国. 二氧化硫与1—己烯的光化学反应动力学[J]. 环境化学, 1995, 14(6): 500-507 |
| |
| 作者姓名： | 郭海忱 杜尧国 |
| |
| 作者单位： | 吉林大学分析测试中心!长春130023(郭海忱)，吉林大学环境科学系!长春130023(杜尧国，林君，徐自力) |
| |
| 基金项目： | 国家自然科学基金资助课题 |
| |
| 摘 要： | 利用ＧＣ／ＭＳ方法研究了ＳＯ２与１－己烯在无氧和有氧体系中光化学反应动力学，确定了ＳＯ２与１－己烯光化学反应的级数，给出了２９３－３３３Ｋ温度范围内总的反应速度常数Ｋ，以及Ｋ与温度的关系、反应的活化能和指前因子。另外，对反应物己醛和２－己酮的生成反应速度常数及其活化能也进行了计算和讨论。
|
| 关 键 词： | 二氧化硫 1－己烯 光化学反应 动力学 |
THE PHOTOCHEMICAL REACTION KINETICS OF SULFUR DIOXIDE AND 1-HEXENE |
| |
| Guo Haichen Du Yaoguo Lin Jun Xu Zili. THE PHOTOCHEMICAL REACTION KINETICS OF SULFUR DIOXIDE AND 1-HEXENE[J]. Environmental Chemistry, 1995, 14(6): 500-507 |
| |
| Authors: | Guo Haichen Du Yaoguo Lin Jun Xu Zili |
| |
| Abstract: | The photochemical reaction kinetics of sulfur dioxide and 1-hexene in the absence or presence of oxygen system were studied using GC and GC/MS methods. The order and rate constants of photochemical reaction of sulfur dioxide and 1-hexene were given. According to Arrhenius equation,frequency factor and activation energies were obtained. In the paper,rate constants and activation energies of formating reaction of hexanal and 2-hexanone were calculated and discussed. |
| |
| Keywords: | sulfur dioxide 1-hexene kinetics of photochemical reaction. |
| 本文献已被 CNKI 维普 等数据库收录！ |
