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模拟酸雨对石刻的腐蚀
引用本文:汤剑,徐飞高,高士祥.模拟酸雨对石刻的腐蚀[J].环境化学,2009,28(2).
作者姓名:汤剑  徐飞高  高士祥
作者单位:1. 污染控制与资源化研究国家重点实验室,南京大学环境学院,南京,210093
2. 污染控制与资源化研究国家重点实验室,南京大学环境学院,南京,210093;南昌大学理学院,南昌,330047
基金项目:江苏省社会发展科技项目 
摘    要:采用pH值分别为5.6,4.5和3.0的人工模拟酸雨,在实验室条件下对具有相同成分的石材进行降雨侵蚀实验,测定了不同pH值下的腐蚀速率.同时,运用XRD和SEM分析酸雨腐蚀的规律.结果表明:酸雨侵蚀首先发生在颗粒间隙处;pH值愈低,腐蚀愈严重;酸雨腐蚀后,石材表面碳酸钙流失严重,其它成分相对富集在表面,而且改变了其原来的形貌.

关 键 词:石刻  酸雨  腐蚀

THE EFFECTS OF SIMULATED ACID RAIN ON THE DETERIORATION OF CARVED STONE
TANG Jian,XU Fei-gao,GAO Shi-xiang.THE EFFECTS OF SIMULATED ACID RAIN ON THE DETERIORATION OF CARVED STONE[J].Environmental Chemistry,2009,28(2).
Authors:TANG Jian  XU Fei-gao  GAO Shi-xiang
Institution:1State Key Laboratory of Pollution Control and Resource Reuse;School of the Environment;Nanjing University;Nanjing;210093;China;2College of Science;Nanchang University;Nanchang;330047;China
Abstract:In order to study the effects of acid rain on carved stone,simulated precipitation erosion experiments were carried out in the laboratory by applying artificially prepared acid rain with pH 5.6,4.5 and 3.0 onto stone materia.Rates of deterioration for different pH were obtained.Meanwhile,deterioration process was monitored with XRD and SEM.The results of experiments indicated that deterioration started among gain boundaries of crystals,and the deterioration increased with the decrease of pH.Calcium carbonat...
Keywords:carved stone  acid rain  deterioration    
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