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中高温条件下活性红KE-3B厌氧脱色特性和机理初探
引用本文:王新海,王天广,马同森,张凌,马骏. 中高温条件下活性红KE-3B厌氧脱色特性和机理初探[J]. 环境科学学报, 2012, 32(11): 2748-2754
作者姓名:王新海  王天广  马同森  张凌  马骏
作者单位:1. 河南大学化学化工学院环境与分析科学研究所,开封,475004
2. 蓝星环境工程有限公司国家环境保护膜分离工程技术中心,北京,101300
基金项目:国家自然科学基金面上项目(No.20875022)
摘    要:以活性红KE-3B为例,考察了中高温条件下盐度、VFAs(挥发性脂肪酸)、污泥的吸附等对其厌氧脱色的影响,从产气量和生物气组分来探讨活性红KE-3B厌氧脱色的形式和程度,并对活性红KE-3B的厌氧脱色机理作初步探讨.结果显示,高温更有利于活性红KE-3B的脱色,脱色率可以达到98%以上,维持高脱色率的最高盐度为600mmol·L-1,并且在脱色过程中,没有发现活性红KE-3B被矿化,其主要脱色形式为初级降解.

关 键 词:厌氧  活性红KE-3B  脱色率  吸附
收稿时间:2012-02-09
修稿时间:2012-04-03

Characteristics and mechanism of anaerobic decolorization of reactive red KE-3B under mesophilic and thermophilic conditions
WANG Xinhai,WANG Tianguang,MA Tongsen,ZHANG Ling and MA Jun. Characteristics and mechanism of anaerobic decolorization of reactive red KE-3B under mesophilic and thermophilic conditions[J]. Acta Scientiae Circumstantiae, 2012, 32(11): 2748-2754
Authors:WANG Xinhai  WANG Tianguang  MA Tongsen  ZHANG Ling  MA Jun
Affiliation:Institute of Environmental and Analytical Sciences, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004;Institute of Environmental and Analytical Sciences, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004;Institute of Environmental and Analytical Sciences, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004;Institute of Environmental and Analytical Sciences, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004;State Environmental Protection Engineering Center for Membrane Technology of China, Blue Star Environmental Engineering Co. Ltd., Beijing 101300
Abstract:Based on an anaerobic batch test system, the effects of salt, volatile fatty acids (VFAs) and sludge adsorption on decolorization of reactive red KE-3B were studied in details. The form and extent of anaerobic decolorization were detected by gas production amount and composition, and the degradation mechanism of reactive red KE-3B reduction was also discussed. The results indicated that the decolorization rate was higher (more than 98%) under thermophilic condition than that under mesophilic condition when the salt concentration was less than 600 mmol·L-1. The evidence of mineralization of reactive red KE-3B was not detected, and we found that the main decolorization form was primary biodegradation.
Keywords:anaerobic  reactive red KE-3B  decolorization rate  adsorption
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