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氨基修饰磁性氧化石墨烯吸附离子型染料性能
引用本文:魏金枝,陈芳妮,孙晓君,张凤鸣,王虹.氨基修饰磁性氧化石墨烯吸附离子型染料性能[J].中国环境科学,2016,36(7):2020-2026.
作者姓名:魏金枝  陈芳妮  孙晓君  张凤鸣  王虹
作者单位:哈尔滨理工大学化学与环境工程学院, 黑龙江 哈尔滨 150040
基金项目:哈尔滨市科技创新人才研究专项资金优秀学科带头人项目(2015RAXXJ006);国家自然科学基金(21501036)
摘    要:采用恒温搅拌法和水热法首次制备磁性三乙烯四胺氧化石墨烯(M-T-GO),并通过SEM和XPS对M-T-GO进行表征.以M-T-GO为吸附剂,分析pH值、吸附时间和初始浓度对阴离子染料酒石黄(TY)和阳离子染料亚甲基蓝(MB)吸附效果的影响.并对吸附动力学和吸附等温线进行拟合.结果表明:M-T-GO对离子型染料的吸附过程符合Langmuir吸附等温式和拟二级反应动力学描述.M-T-GO对TY和MB具有较好的吸附性能,饱和吸附量分别为157.23mg/g和169.49mg/g.与GO相比,M-T-GO对离子型染料的吸附效果更优异,同时具有快速分离和易再生的优点.

关 键 词:氧化石墨烯  三乙烯四胺  磁性  吸附  离子型染料  
收稿时间:2015-12-15

Adsorption performance of amino functionalized magnetic graphene oxide composite to ionic dyes.
WEI Jin-zhi,CHEN Fang-ni,SUN Xiao-jun,ZHANG Feng-ming,WANG Hong.Adsorption performance of amino functionalized magnetic graphene oxide composite to ionic dyes.[J].China Environmental Science,2016,36(7):2020-2026.
Authors:WEI Jin-zhi  CHEN Fang-ni  SUN Xiao-jun  ZHANG Feng-ming  WANG Hong
Institution:College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Haerbin 150040, China
Abstract:Magnetic Triethylene-tetramine Graphene oxide (M-T-GO) was firstly synthesized by constant temperature stirring and hydrothermal methods in this work, and characterized by Scanning electron microscope (SEM) and X-ray photoelectron spectrum (XPS). Adsorption capacity of ionic dyes on M-T-GO under different pH, adsorption time and initial concentration were investigated. At the same time adsorption kinetics and adsorption isotherm were fitted respectively. Pseudo-second-order model and Langmuir model fitted the adsorption of ionic dyes on M-T-GO. The adsorption property of M-T-GO for TY and MB was outstanding and the saturated adsorption capacities were 157.23mg/g and 169.49mg/g, respectively. Compared with GO, M-T-GO could remove ionic dyes more effectively. Moreover, M-T-GO made separation easy in the foreign magnetic field and possessed good performance of regeneration.
Keywords:graphene oxide  triethylene tetramine  magnetic  adsorption  ionic dyes  
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