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Aerosol scattering coefficients and major chemical compositions of fine particles observed at a rural site in the central Pearl River Delta, South China
Authors:Xinming Wang  Xiang Ding  Xiaoxin Fu  Quanfu He  Shaoyi Wang  Franc&#;is Bernar  Xiuying Zhao and Dui Wu
Institution:State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China;State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China;Graduate University of Chinese Academy of Sciences, Beijing 100049, China;Graduate University of Chinese Academy of Sciences, Beijing 100049, China;Guangzhou Environmental Monitoring Center, Guangzhou 510030, China;State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China;State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China; Graduate University of Chinese Academy of Sciences, Beijing 100049, China;Institute of Tropical and Marine Meteorology, China Meteorological Agency, Guangzhou 510080, China
Abstract:During November-December 2010 aerosol scattering coefficients were monitored using a single-waved (525 nm) Nephelometer at a regional monitoring station in the central Pearl River Delta region and 24-hr fine particle (PM2.5) samples were also collected during the period using quartz filters for the analysis of major chemical components including organic carbon (OC), elemental carbon (EC), sulfate, nitrate and ammonium. In average, these five components accounted for about 85% of PM2.5 mass and contributed 42% (OC), 19% (SO42-), 12% (NO3-), 8.4% (NH4+) and 3.7% (EC), to PM2.5 mass. A relatively higher mass scattering efficiency of 5.3 m2/g was obtained for fine particles based on the linear regression between scattering coefficients and PM2.5 mass concentrations. Chemical extinction budget based on IMPROVE approach revealed that ammonium sulfate, particulate organic matter, ammonium nitrate and EC in average contributed about 32%, 28%, 20% and 6% to the light extinction coefficients, respectively.
Keywords:scattering coefficients  visibility  fine particle (PM2  5)  chemical compositions
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