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Photooxidation of diphenylmethane and 1,2,3,4-tetrahydronaphthalene as liquid film on water
Authors:Gunnar Aksnes  Arve Iversen
Institution:Chemical Institute, University of Bergen, N-5014, Norway
Abstract:The rate and product composition are analysed during photooxidation of diphenylmethane and tetralin (1,2,3,4-tetrahydronaphthalene) spread as liquid film on water. The data obtained from various reaction conditions (varying light, temperature, sensitizer and inhibitor) seem to conform the assumption that the photooxidation of these compounds is primarily initiated through a photoexcited hydrocarbon/oxygen collision complex.
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