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粗壮女贞中的新单萜配糖体
引用本文:田军,孙汉董. 粗壮女贞中的新单萜配糖体[J]. 应用与环境生物学报, 1999, 5(5): 501-506
作者姓名:田军  孙汉董
作者单位:1. 中国科学院昆明植物研究所植物化学开放实验室,昆明,650204;中国科学院成都生物研究所天然药物开放实验室,成都,610041
2. 中国科学院昆明植物研究所植物化学开放实验室,昆明,650204
基金项目:中国科学院成都地奥科学基金 
摘    要:从粗壮女贞(Ligustrum robustum)叶子中分离鉴定了4个新的单萜配糖体,命名为粗壮女贞甙D、G、H和L.通过滤谱及化学方法,它们分别鉴定为香叶醇3‘-O-μ-L-南鼠李糖基-4’-顺式香豆酰基-β-D-吡喃葡萄糖甙(1),6-羟基-3,7-二甲基-2E,7葵二烯醇3‘-O-α-L-吡喃鼠李糖基-4’反式香豆酰基-β-D-吡喃葡萄糖甙(2),6-羟基-3,7-二甲基-2E,7-葵二烯醇

关 键 词:粗壮女贞 单萜配糖体 木樨科
修稿时间:1998-12-04

NEW MONOTERPENOID GLYCOSIDES FROM LIGUSTRUM ROBUSTUM
TIAN Jun,SUN Handong. NEW MONOTERPENOID GLYCOSIDES FROM LIGUSTRUM ROBUSTUM[J]. Chinese Journal of Applied and Environmental Biology, 1999, 5(5): 501-506
Authors:TIAN Jun  SUN Handong
Abstract:Four new monoterpenoid glycosides, named ligurobustosides D, G, H and L, were isolated from the leaves of Ligustrum robustum. On the basis of spectral and chemical methods, their structures were identified as geraniol 3′-O-α-L-rhamnopyranosyl-4′-cis-p-coumaroyl-β-D-glucopyranoside(1),6-hydroxy-3,7-dimethyl-2E,7-octadienyl-1-ol 3′-O-α-L-rhamnopyranosyl-4′-trans-p-coumaroyl-β-D-glucopyranoside(2), 6-hydroxy-3,7-dimethyl-2E,7-octadienyl-1-ol 3′-O-α-L-rhamnopyranosyl-4′-cis-p-coumaroyl-β-D-glucopyranoside(3) and 6,7-dihydroxy-3,7-dimethyl-2E-octaenyl-1-ol 3′-O-α-L-rhamnopyranosyl-4′-cis-p-coumaroyl-β-D-glucopyranoside(4), respectively. In addition, seven known compounds, apigenin(5), cosmosiin(6), rhoifolin(7), D-sorbitol(8), arteoside(9), β-sitosterol(10) and oleanolic acid (11) were also obtained.
Keywords:Ligustrum robustum  monoterpenoid glycosides  Oleaceae
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