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A chemical characterization of atmospheric aerosol in Sapporo
Institution:1. University of Chinese Academy of Sciences, Beijing 100049, China;2. Huairou Eco-Environmental Observatory, Chinese Academy of Sciences, Beijing 101408, China;3. Beijing Institute of Aerospace Testing Technology, Beijing 100074, China;4. Peking University, College Environmental Science & Engineering, Beijing 100871, China;5. State Key Joint Lab Environmental Simulation & Pollution Control, Beijing 100871, China;1. State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry (LAPC), Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;1. CSIR-National Physical Laboratory, Dr. K S Krishnan Road, New Delhi 110 012, India;2. CSIR-National Environmental Engineering Research Institute (DZL), New Delhi 110 028, India
Abstract:Monthly mean chemical composition of aerosol with diameter less than 8 μm was identified in Sapporo in 1982. The mass of aerosol was made up of nine components: elemental C, organics, SO42−, NO3, NH4+, Cl, Na+, soil particles and water. The concentrations of carbonaceous particles (elemental C and organics) was relatively high (12.7–16.0μ m−3) in autumn and winter (October–February) due to emission from domestic heating and comprised 36–41% of total aerosol mass. Higher concentration of soil particles was observed in spring (March–May) (9.7–13.1 μg m−3) and comprised 22–29% of total aerosol mass due to suspension by strong wind. On the other hand, the concentration of excess SO42− (non-sea salt SO42−), which ranged from 2.6–5.2 μg m−3, did not change remarkably with season, and the fraction of excess sulfate increased to 21% in summer (July–August) probably due to photochemical transformation from SO2. Nitrate concentration was far less than that of SO42− throughout the year in Sapporo.
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