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土壤中锰氧化物的形态及其化学提取方法综述
引用本文:李颖,顾雪元.土壤中锰氧化物的形态及其化学提取方法综述[J].环境化学,2022,41(1):9-21.
作者姓名:李颖  顾雪元
作者单位:南京大学环境学院,污染控制与资源化国家重点实验室,南京,210023
基金项目:国家重点研发项目(2018YFC1800602);;国家自然科学基金(21876080);;江苏省社会发展项目(BE2015708)资助~~;
摘    要:土壤中锰元素主要来自于成土母质,风化后的锰主要以锰氧化物形式存在于土壤中.锰氧化物因具有比表面积大、表面电荷低、对金属的亲合力强、氧化还原电位高等特性,对土壤中痕量金属的环境行为存在重要影响.化学提取方法是研究土壤中不同固相组分的重要手段.本文首先从土壤中锰的来源及主要存在形态出发,介绍了不同价态锰(+2、+3、+4)...

关 键 词:土壤  锰氧化物  特性  单一提取  连续提取

Soil manganese oxides and its extraction methods:A review
LI Ying,GU Xueyuan.Soil manganese oxides and its extraction methods:A review[J].Environmental Chemistry,2022,41(1):9-21.
Authors:LI Ying  GU Xueyuan
Institution:(School of the Environment,State Key Laboratory of Pollution Control and Resource Reuse,Nanjing University,Nanjing,210023,China)
Abstract:Manganese(Mn)in soil mainly comes from parent minerals and weathered Mn mainly exists in soil in forms of Mn oxides.Manganese oxides have large specific surface area,low surface charge,strong affinity for metals,and high redox potential,hence they have important effects on environmental behavior of trace metals in soil.Chemical extraction is an important method to study the solid-phase components in soil.At first,this review introduced the source and existence of Mn oxides with different valences(+2,+3,+4)in soil,and the factors affecting the transformation of Mn;secondly,we summarized different types of Mn oxides in soil and their surface characteristics,adsorption abilities,redox properties;finally,the single extraction and the sequential extraction method of different forms of Mn in soil are summarized,as well as the application of the extraction method.This review provides a reference for the further study of Mn oxides in the soil.
Keywords:soil  manganese oxide  properties  single extraction  sequential extraction  
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