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污水生物处理过程药品及个人护理品转化产物识别研究进展
引用本文:吴刚,耿金菊,李想,于清淼,许柯,任洪强. 污水生物处理过程药品及个人护理品转化产物识别研究进展[J]. 环境化学, 2022, 41(1): 57-69. DOI: 10.7524/j.issn.0254-6108.2020110603
作者姓名:吴刚  耿金菊  李想  于清淼  许柯  任洪强
作者单位:南京大学环境学院,污染控制与资源化研究国家重点实验室,南京,210023
基金项目:江苏省自然科学基金(BK20180010);;国家自然科学基金(21677071,51978327);;江苏省研究生科研创新基金(KYCX20_0045)资助~~;
摘    要:药品及个人护理品(pharmaceuticals and personal care products,PPCPs)在污水生物处理过程会发生生物及化学转化从而生成转化产物,某些转化产物较母体化合物毒性更高.目前对PPCPs转化产物关注不够,转化产物识别方法不明确.本文介绍了污水中PPCPs转化产物的识别流程,系统阐述了...

关 键 词:药品及个人护理品  转化产物  识别  污水  生物处理

Identification of transformation products of PPCPs during wastewater biological treatment processes
WU Gang,GENG Jinju,LI Xiang,YU Qingmiao,XU Ke,REN Hongqiang. Identification of transformation products of PPCPs during wastewater biological treatment processes[J]. Environmental Chemistry, 2022, 41(1): 57-69. DOI: 10.7524/j.issn.0254-6108.2020110603
Authors:WU Gang  GENG Jinju  LI Xiang  YU Qingmiao  XU Ke  REN Hongqiang
Affiliation:(State Key Laboratory of Pollution Control and Resource Reuse,School of the Environment,Nanjing University,Nanjing,210023,China)
Abstract:Pharmaceuticals and personal care products(PPCPs)are subject to biotic and abiotic transformation in wastewater,which can cause the formation of transformation products(TPs).Some TPs of PPCPs are more toxic than parent compounds.However,the attention paid on TPs is insufficient and the methods on identifying TPs of PPCPs in wastewater are scare.In this study,the workflows of identification of TPs formed from PPCPs during wastewater biological treatment processes were introduced.The details on sample acquisition,sample preparation,detecting by liquid chromatography-high resolution mass spectrometry and data analysis were elaborated.Based on the procedure of identification of TPs mentioned above,the details of identifying TPs from various PPCPs were compared and the proper methods were put forward to fully identifying TPs of PPCPs in wastewater.Accordingly,the identified TPs and involved transformation reactions of various PPCPs such as antibiotic,hormones,non-steroidal anti-inflammatory drugs,psychotropic pharmaceuticals and others were stated in detail.Present review provides a comprehensive picture of TPs from various PPCPs in WWTPs.
Keywords:PPCPs  transformation products  identification  sewage  biological treatment.
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