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Ggum-poly(Itaconic Acid) Based Superabsorbents Via Two-Step Free-Radical Aqueous Polymerization for Environmental and Antibacterial Applications
Authors:Reena Sharma  Susheel Kalia  Balbir S Kaith  Amit Kumar  Pankaj Thakur  D Pathania  Manoj K Srivastava
Institution:1.School of Chemistry,Shoolini University,Solan,India;2.Department of Chemistry, Army Cadet College Wing,Indian Military Academy,Dehradun,India;3.Department of Chemistry,Dr. B.R. Ambedkar National Institute of Technology,Jalandhar,India;4.Department of Physics, Army Cadet College Wing,Indian Military Academy,Dehradun,India
Abstract:Ggum-based conducting hydrogels possessing dye removal and antibacterial property were developed by two-step free-radical aqueous polymerization method. Conductivity was introduced with polyaniline (PANI) chains incorporated within the crosslinked network of Ggum-poly(itaconic acid) superabsorbent. The material properties of the synthesized samples were characterized using FTIR spectroscopy, thermal analysis and scanning electron microscopy techniques. Results showed that synthesized samples exhibited the best antibacterial activity against Gram-positive bacteria. Synthesized samples were found to be effective in removal of toxic methylene blue (MB) dye from the waste water. The adsorption kinetics of superabsorbents has been described by using pseudo first and pseudo second order kinetics models. Furthermore, application of hydrogels to improve the water retention properties of different soils was also studied for agricultural purpose.
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