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Copper biosorption on immobilized seaweed biomass: Column breakthrough characteristics
作者姓名:K. H. Chu  M. A. Hashim
作者单位:Department of
基金项目:Acknowledgements The authors thank Miss H. N. Tan for technical assistance.
摘    要:The biosorption of copper by the brown seaweed Sargassum baccularia,immobilized onto polyvinyl alcohol(PVA)gel beads, was investigated with fixed-bed experiments.Laboratory-scale column tests were performed to determine breakthrough curves with varying flow rates and feed concentrations.A theoretical fixed-bed model,known as the Bohart-Adams equation,was evaluated in simulating the experimental breakthrough curves.The Bohart-Adams model qualitatively predicted the breakthrough trends.PVA- immobilized seaweed biomass beads were amenable to efficient regeneration with aqueous solution containing the chelating agent ethylenediaminetetraacetic acid(EDTA).The biosorbent retained most of its original uptake capacity over three cycles of use.The excellent reusability of the biosorbent could lead to the development of a viable metal remediation technology.

关 键 词:吸附  生物吸着  海藻  乙醇
收稿时间:2 October 2006
修稿时间:2006-10-02

Copper biosorption on immobilized seaweed biomass: Column breakthrough characteristics
K. H. Chu,M. A. Hashim.Copper biosorption on immobilized seaweed biomass: Column breakthrough characteristics[J].Journal of Environmental Sciences,2007,19(8):928-932.
Authors:K H Chu and M A Hashim
Institution:1. Honeywell Process Solutions, 17 Changi Business Park, Central 1, Singapore 486073
2. Department of Chemical Engineering, University of Malaya, 50603 Kuala Lumpur, Malaysia
Abstract:The biosorption of copper by the brown seaweed Sargassum baccularia, immobilized onto polyvinyl alcohol (PVA) gel beads, was investigated with fixed-bed experiments. Laboratory-scale column tests were performed to determine breakthrough curves with varying flow rates and feed concentrations. A theoretical fixed-bed model, known as the Bohart-Adams equation, was evaluated in simulating the experimental breakthrough curves. The Bohart-Adams model qualitatively predicted the breakthrough trends. PVA-immobilized seaweed biomass beads were amenable to efficient regeneration with aqueous solution containing the chelating agent ethylenediaminetetraacetic acid (EDTA). The biosorbent retained most of its original uptake capacity over three cycles of use. The excellent reusability of the biosorbent could lead to the development of a viable metal remediation technology.
Keywords:adsorption  biosorption  fixed bed  immobilized algae  polyvinyl alcohol  biomass  biosorption  Copper  characteristics  breakthrough  reusability  lead  development  metal  remediation  technology  original  uptake capacity  cycles  EDTA  efficient  regeneration  aqueous solution  containing  chelating agent
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