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广州市灰霾期PM10的化学组成对能见度的影响
引用本文:郭送军,谭吉华,段菁春,马永亮,盛国英,傅家谟. 广州市灰霾期PM10的化学组成对能见度的影响[J]. 环境监测管理与技术, 2012, 24(3): 24-28
作者姓名:郭送军  谭吉华  段菁春  马永亮  盛国英  傅家谟
作者单位:1. 广西大学环境学院,广西南宁530004;中国科学院计算地球动力学重点实验室,中国科学院研究生院,北京100049
2. 中国科学院计算地球动力学重点实验室,中国科学院研究生院,北京100049;清华大学环境学院,北京100084
3. 中国科学院广州地球化学研究所,有机地球化学国家重点实验室,广东广州510640
4. 中国科学院计算地球动力学重点实验室,中国科学院研究生院,北京100049
基金项目:国家自然科学基金资助项目,国家重点实验室专项基金资助项目,广西大学科研基金资助项目
摘    要:采集广州市大气可吸入颗粒物(PM10)样品,并分别对冬、夏两季灰霾和非灰霾期PM10中有机碳(OC)、元素碳(EC)和水溶性离子进行分析。广州市灰霾期大气PM10中的主要化学成分按质量浓度大小排序为OC>NO3->SO24->NH4+>EC(非灰霾期则依次为OC>SO24->EC>NH4+>NO3-),其质量浓度分别为非灰霾期的4.7、12.5、3.7、3.2和2.3倍。相关性分析表明,灰霾期总碳[TC(OC+EC)]及NO3-的质量浓度对大气能见度的降低起主要作用,而非灰霾期则主要是TC和SO24-。

关 键 词:灰霾  可吸入颗粒物  化学组分  能见度  广州

Impact of Chemical Compositions in PM10 on Visibility during Haze Period in Guangzhou
GUO Song-jun , TAN Ji-hua , DUAN Jing-chun , MA Yong-liang , SHENG Guo-ying , FU Jia-mo. Impact of Chemical Compositions in PM10 on Visibility during Haze Period in Guangzhou[J]. The Administration and Technique of Environmental Monitoring, 2012, 24(3): 24-28
Authors:GUO Song-jun    TAN Ji-hua    DUAN Jing-chun    MA Yong-liang    SHENG Guo-ying    FU Jia-mo
Affiliation:1.School of Environment,Guangxi University,Nanning,Guangxi 530004,China;2.Key Laboratory of Computational Geodynamics,College of Earth Science,Graduate School of Chinese Academy of Sciences, Beijing 100049,China;3.School of Environment,Tsinghua University,Beijing 100084,China;4.State Key Laboratory of Organic Geochemistry,Guangzhou Institute of Geochemistry,Chinese Academy of Sciences, Guangzhou,510640,China)
Abstract:PM10 samples were collected in Guangzhou during haze and normal days in the summer and the winter.Water-soluble ions,organic carbon(OC) and element carbon(EC) in PM10 were analyzed.Concentrations of the component in PM10 descended in the order of OCNO-3SO2-4NH+4EC in haze days,(but OCSO2-4ECNH+4NO-3 in normal days) which were 4.7,12.5,3.7,3.2 and 2.3 times than that in normal days,respectively.Correlative analysis showed that concentrations of TC(OC+EC) and NO-3 had significantly negative effect on visibility in haze days,but TC and SO2-4 had that in normal days.
Keywords:Haze  PM10  Chemical composition  Visibility  Guangzhou
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