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Estimation of Cumulative Frequency Distribution for Carbon Monoxide Concentration from Wind-Speed Data, in Buenos Aires (Argentina)
Authors:Nicolás A. Mazzeo  Laura E. Venegas
Affiliation:(1) National Scientific and Technological Research Council (CONICET), Department of Atmospheric Science and the Oceans, Faculty of Sciences, University of Buenos Aires, Ciudad Universitaria, Pab. 2., Buenos Aires, Argentina
Abstract:In this article we apply and test a methodology to estimate cumulative frequency distribution for air pollutant concentration from wind-speed data. We use the inverse relationship after Simpson et al. (Atmospheric Environment, 19, 75–82, 1985) between the opposing percentile values in the statistical distributions for air pollutant concentrations and wind-speed data. This relationship is valid, irrespective of the statistical distributions of both variables, if an inverse relationship between them is also applicable. The available data are five years of 8-h average carbon monoxide concentration and 8-h mean wind-speed, observed in Buenos Aires (Argentina). The performance of the obtained empirical expressions in estimating cumulative frequency distributions for 8-h CO is statistically evaluated. The results show that it is possible to obtain an acceptable cumulative frequency distribution for 8-h CO concentration at the site if the cumulative frequency distribution for wind-speed is known. Q–Q plots show a good agreement between estimated and observed values. From our data, the mean relative error of the estimations was found to be as much as 8.0%.
Keywords:box models  carbon monoxide data  cumulative frequency distribution  exceedances of air quality standard  percentile analysis  urban air pollution
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