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ANTIDEGRADATION WATER QUALITY CRITERIA FOR THE DELAWARE RIVER: A DISTRIBUTION-FREE STATISTICAL APPROACH1
Authors:F Jay Breidt  Duane C. Roes  Joel I. Wagner  Mark D. Flora
Abstract:ABSTRACT: Existing water quality for the Middle Delaware Scenic and Recreational River is significantly better than is required by current standards, leaving a potential for degradation. A method is presented for deriving candidate antidegradation water quality criteria for this segment of the Delaware River using statistical analysis of historic (ambient) water quality data. Data for 34 water quality parameters are first evaluated for data density, serial correlation, trend, seasonality, and other factors. These preliminary analyses are based on observation of data plots and application of distribution-free statistical techniques that are insensitive to outliers and are robust to relatively mild violations of basic assumptions. Data for 12 of the parameters have sufficient density for further analysis and can reasonably be modeled as independent and identically distributed over time (either seasonally or for the entire data sets). For these 12 parameters, distribution-free statistical methods are developed and used to derive intervals within which there is high confidence (usually greater than 95 percent) that the quantiles with potential use as anti-degradation criteria (the 0.85th, 0.90th, and 0.95th quantiles in this study) for a particular parameter lie.
Keywords:water quality  standards  criteria  antidegradation  distribution-free statistics  nonparametric statistics  Delaware River
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