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短程硝化的生化机理及其动力学
引用本文:彭永臻,孙洪伟,杨庆.短程硝化的生化机理及其动力学[J].环境科学学报,2008,28(5):817-824.
作者姓名:彭永臻  孙洪伟  杨庆
作者单位:北京工业大学,北京市水质科学与水环境恢复工程重点实验室,北京,100022
基金项目:国家科技支撑计划重点项目 , 北京工业大学第六届研究生科技基金
摘    要:短程硝化的生化反应机理和动力学是生物脱氮技术的理论基础,同时也是生物脱氮工艺设计、运行科学化和合理化的重要依据.基于短程硝化的生化机理、氨氧化菌的电子传递(能量产生)模式,从微生物学和化学计量学两个方面详细论述了短程硝化一系列复杂的生化反应过程.由此可知,短程硝化是一个涉及多种酶及多种中间产物,并伴随着电子(能量)传递的复杂生化反应过程,是基质(NH4 -N)利用(产能代谢)和微生物(氨氧化菌)增殖(合成代谢)两类反应的综合,因此,研究氨氮比利用速率和氨氧化菌比增殖速率动力学则是对短程硝化反应的深层次研讨.并建议采用积分法和微分法来确定动力学参数μnmax、KN、vnmax.

关 键 词:短程硝化  生化机理  动力学  电子传递  化学计量学
文章编号:0253-2468(2008)05-817-08
收稿时间:6/1/2007 12:00:00 AM
修稿时间:2007年6月1日

The biochemical reaction mechanism and kinetics of partial nitrification
PENG Yongzhen,SUN Hongwei and YANG Qing.The biochemical reaction mechanism and kinetics of partial nitrification[J].Acta Scientiae Circumstantiae,2008,28(5):817-824.
Authors:PENG Yongzhen  SUN Hongwei and YANG Qing
Institution:Key Laboratory of Beijing Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing 100022,Key Laboratory of Beijing Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing 100022 and Key Laboratory of Beijing Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing 100022
Abstract:The biochemical reaction mechanism and kinetics of partial nitrification are the foundation of biological nitrogen removal and they are important for biological denitrification process design and proper operation. The complex biochemical reaction of partial nitrification is described from the microbiology and stoichiometry on the basis of the electron flow (energy production) pathway. By these, we know that partial nitrification involves a series of complex biochemical reactions concerning many intermediates, accompanied with electron flow (energy production). At the same time, it is the synthesis of two reactions-ammonia-N utilization and ammonia-oxidizing bacterial growth which need further study. Integral and differential methods are adapted to obtain the values of the kinetics constants.
Keywords:partial nitrification  biochemical mechanism  kinetics  electron flow  stoichiometry
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