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Potentiometric techniques applied to the modelling of actinide migration in natural water systems†
Authors:Jordi Bruno  Ingmar Grenthe
Institution:Department of Inorganic Chemistry , Royal Institute of Technology , Stockholm, S‐100 44, Sweden
Abstract:The utility of potentiometric techniques applied to environmental problems is discussed. The applicability of this technique to the estimation of thermodynamic quantities important for the modelling of uranium migration in natural waters is demonstrated. An experimental methodology for the determination of the UO2(s) solubility product and the UO2+/U4+ redox potentials is proposed.
Keywords:Potentiometric techniques  uranium migration  natural waters  environmental problems  ground water  unclear waste repositories
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