Leaching of copper,chromium and arsenic in a soil of south west Victoria,Australia

The movement of copper, chromium and arsenic originating from samples of the wood preservative Tanalith® through mildly acidic, sandy loam soil was investigated. Small, undisturbed soil cores (of dimensions 15 × 15 × 15 cm) were removed from the topsoil of a paddock adjacent to the Glenelg River in the Western District of Victoria, Australia. The paddock soils were thin (<30cm) greyish brown, mildly acidic, sandy loams with a moderate organic carbon content (2–5%) overlying a limestone cap. Tanalith® was applied to the surface of the cores which were then irrigated with deionised water at approximately 30 mm day^‐1. Copper concentrations in all leachate remained at background levels throughout the experiment, and this element was found to be immobilised in the top 4 cm of the soil. Up to 29% of the applied dose of chromium was detected in the leachate, with breakthrough occurring within 20 days of Tanalith® application. Up to 13% ofthe applied dose ofarsenic was detected in the leachate, although in this case breakthrough was not observed until 25 days after Tanalith® application and leachate concentrations were still rising when the experiment came to a close. Significant concentrations of arsenic and chromium were found in the top 6 cm of the soil profile.