The Dechlorination of H6CDD,OCDD and OCDF on an Alumina support: Elucidation of the isomer pattern by multi linear regression and thermodynamic data |
| |
| Authors: | Mirjam H Schoonenboom Kees Olie Harrie AJ Govers |
| |
| Institution: | Department of Environmental and Toxicological Chemistry, Amsterdam Research Institute of Substances in Ecosystems , University of Amsterdam , Nieuwe Achtergracht 166, Amsterdam, 1018 WV, The Netherlands |
| |
| Abstract: | The dechlorination of OCDD, OCDF and 1,2,3,4,7,8‐H6CDD is studies on an alumina support impregnated with activated carbon, copper chloride and potassium chloride. There is a high correlation between the isomer pattern found after dechlorination and molecular structure properties. We also found a substantial correlation between the isomer pattern and the Gibbs free energy of formation of the individual isomers. This suggests a thermodynamically controlled process. |
| |
| Keywords: | Dechlorination 1 2 3 4 7 8 ‐H6CDD OCDD OCDF isomer pattern molecular structure properties Gibbs free energy of formation |
|
|
